O. Kazantsev, K. V. Shirshin, P. V. Kornienko, A. P. Sivokhin
{"title":"聚(甲基)丙烯酰亚胺泡沫合成的成就与展望。聚合物前体的热酰亚胺化阶段","authors":"O. Kazantsev, K. V. Shirshin, P. V. Kornienko, A. P. Sivokhin","doi":"10.1177/0262489320934258","DOIUrl":null,"url":null,"abstract":"The review summarises the trends in the development of research on the synthesis of polymethacrylimides (PMIs) and polyacrylimides by the method of intramolecular thermal imidisation of (meth)acrylic polymers. Along with the widely used industry variant of PMI foam of the ‘Rohacell’ series based on bulk copolymers of methacrylonitrile and methacrylic acid, intensive research on alternative variants began after 2005. This review describes the main and side reactions when using polymer precursors of different structures as well as the effect of precursor composition and structure on the properties of the resulting poly(meth)acrylimides. It has been shown that the achievements of the last 15 years provide a basis for reducing the cost of poly(meth)acrylimides which will significantly expand the areas and scale of their application.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"40 1","pages":"31 - 52"},"PeriodicalIF":1.3000,"publicationDate":"2020-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489320934258","citationCount":"2","resultStr":"{\"title\":\"Achievements and prospects for the synthesis of poly(meth)acrylimide foams. Stage of the thermal imidisation of polymer precursors\",\"authors\":\"O. Kazantsev, K. V. Shirshin, P. V. Kornienko, A. P. Sivokhin\",\"doi\":\"10.1177/0262489320934258\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The review summarises the trends in the development of research on the synthesis of polymethacrylimides (PMIs) and polyacrylimides by the method of intramolecular thermal imidisation of (meth)acrylic polymers. Along with the widely used industry variant of PMI foam of the ‘Rohacell’ series based on bulk copolymers of methacrylonitrile and methacrylic acid, intensive research on alternative variants began after 2005. This review describes the main and side reactions when using polymer precursors of different structures as well as the effect of precursor composition and structure on the properties of the resulting poly(meth)acrylimides. It has been shown that the achievements of the last 15 years provide a basis for reducing the cost of poly(meth)acrylimides which will significantly expand the areas and scale of their application.\",\"PeriodicalId\":9816,\"journal\":{\"name\":\"Cellular Polymers\",\"volume\":\"40 1\",\"pages\":\"31 - 52\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2020-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1177/0262489320934258\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cellular Polymers\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1177/0262489320934258\",\"RegionNum\":4,\"RegionCategory\":\"医学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, BIOMATERIALS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cellular Polymers","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1177/0262489320934258","RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, BIOMATERIALS","Score":null,"Total":0}
Achievements and prospects for the synthesis of poly(meth)acrylimide foams. Stage of the thermal imidisation of polymer precursors
The review summarises the trends in the development of research on the synthesis of polymethacrylimides (PMIs) and polyacrylimides by the method of intramolecular thermal imidisation of (meth)acrylic polymers. Along with the widely used industry variant of PMI foam of the ‘Rohacell’ series based on bulk copolymers of methacrylonitrile and methacrylic acid, intensive research on alternative variants began after 2005. This review describes the main and side reactions when using polymer precursors of different structures as well as the effect of precursor composition and structure on the properties of the resulting poly(meth)acrylimides. It has been shown that the achievements of the last 15 years provide a basis for reducing the cost of poly(meth)acrylimides which will significantly expand the areas and scale of their application.
期刊介绍:
Cellular Polymers is concerned primarily with the science of foamed materials, the technology and state of the art for processing and fabricating, the engineering techniques and principles of the machines used to produce them economically, and their applications in varied and wide ranging uses where they are making an increasingly valuable contribution.
Potential problems for the industry are also covered, including fire performance of materials, CFC-replacement technology, recycling and environmental legislation. Reviews of technical and commercial advances in the manufacturing and application technologies are also included.
Cellular Polymers covers these and other related topics and also pays particular attention to the ways in which the science and technology of cellular polymers is being developed throughout the world.