Yaxuan Zhu, Yuxin Wang, Yuexin Wang, Gang Liu, Qian Zhang
{"title":"改性MgO晶须对油浸单体铸造尼龙力学和摩擦学性能的影响","authors":"Yaxuan Zhu, Yuxin Wang, Yuexin Wang, Gang Liu, Qian Zhang","doi":"10.1134/S1560090423700963","DOIUrl":null,"url":null,"abstract":"<p>The magnesium oxide whisker was commonly used as reinforcement for polymer. In this study, magnesium oxide whisker was firstly modified by γ-aminopropyl triethoxysilane and <i>n</i>-octadecylamine activated by <i>N</i>,<i>N</i>'-carbonyldiimidazole. Then the modified magnesium oxide whisker was introduced into oil-impregnated monomer casting nylon. The final composite was obtained by in situ polymerization. The mechanical and tribological properties of composite with different contents of modified magnesium oxide whisker were investigated. The results showed that the mechanical and tribological performances of the composites were observably improved by growth of tensile strength, flexural strength, elongation at break, and impact strength. The tribological test results indicated that reduction in the frictional coefficient and the abrasion loss was achieved. The surface lipophilicity of composites obviously increased also. This work provided a simple method for designing composites with excellent mechanical and frictional properties which may greatly broaden the application potential of composites.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"65 3","pages":"372 - 386"},"PeriodicalIF":1.0000,"publicationDate":"2023-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Effect of Modified MgO Whisker on Mechanical and Tribological Properties of Oil-Impregnated Monomer Casting Nylon\",\"authors\":\"Yaxuan Zhu, Yuxin Wang, Yuexin Wang, Gang Liu, Qian Zhang\",\"doi\":\"10.1134/S1560090423700963\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The magnesium oxide whisker was commonly used as reinforcement for polymer. In this study, magnesium oxide whisker was firstly modified by γ-aminopropyl triethoxysilane and <i>n</i>-octadecylamine activated by <i>N</i>,<i>N</i>'-carbonyldiimidazole. Then the modified magnesium oxide whisker was introduced into oil-impregnated monomer casting nylon. The final composite was obtained by in situ polymerization. The mechanical and tribological properties of composite with different contents of modified magnesium oxide whisker were investigated. The results showed that the mechanical and tribological performances of the composites were observably improved by growth of tensile strength, flexural strength, elongation at break, and impact strength. The tribological test results indicated that reduction in the frictional coefficient and the abrasion loss was achieved. The surface lipophilicity of composites obviously increased also. This work provided a simple method for designing composites with excellent mechanical and frictional properties which may greatly broaden the application potential of composites.</p>\",\"PeriodicalId\":739,\"journal\":{\"name\":\"Polymer Science, Series B\",\"volume\":\"65 3\",\"pages\":\"372 - 386\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2023-06-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Science, Series B\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1560090423700963\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1560090423700963","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Effect of Modified MgO Whisker on Mechanical and Tribological Properties of Oil-Impregnated Monomer Casting Nylon
The magnesium oxide whisker was commonly used as reinforcement for polymer. In this study, magnesium oxide whisker was firstly modified by γ-aminopropyl triethoxysilane and n-octadecylamine activated by N,N'-carbonyldiimidazole. Then the modified magnesium oxide whisker was introduced into oil-impregnated monomer casting nylon. The final composite was obtained by in situ polymerization. The mechanical and tribological properties of composite with different contents of modified magnesium oxide whisker were investigated. The results showed that the mechanical and tribological performances of the composites were observably improved by growth of tensile strength, flexural strength, elongation at break, and impact strength. The tribological test results indicated that reduction in the frictional coefficient and the abrasion loss was achieved. The surface lipophilicity of composites obviously increased also. This work provided a simple method for designing composites with excellent mechanical and frictional properties which may greatly broaden the application potential of composites.
期刊介绍:
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed