超声与Ni/ZSM-5催化剂联合催化甘油制乙醇

Eksergi Pub Date : 2023-03-02 DOI:10.31315/e.v20i1.8167
Devi Indrasari Mustopa Putri, S. Sumari, Handoko Darmokoesomo, G. Supriyanto, N. Nugroho
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引用次数: 0

摘要

:用作替代燃料的生物柴油产量增加,导致甘油形式的副产品增加。这种甘油副产物可以通过将其转化为其他化合物如乙醇来利用。从甘油生产乙醇需要一种可以分解甘油分子大小的催化剂,沸石就是其中之一。一种很好使用的沸石是ZSM-5,因为这种类型的沸石具有高度的热稳定性、酸稳定性和选择性。ZSM-5的催化性能可以通过浸渍过渡基团的金属来改善,在本研究中使用Ni(镍)。结果表明,催化剂Ni/ZSM-5的总酸度为0.920mmol/g,比表面积为138.754m2/g。在超声处理4小时时产生最高的乙醇产物,为20.362%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Conversion of Glycerol to Ethanol by Integrating Ultrasonic and Ni/ZSM-5 Catalyst
: The increased production of biodiesel which is used as an alternative fuel has led to an increase in the by-product in the form of glycerol. This glycerol byproduct can be utilized by converting it into other compounds such as ethanol. The production of ethanol from glycerol requires a catalyst that can break down the molecular size of glycerol, one of which is zeolite. One type of zeolite that is good to use is ZSM-5, because this type of zeolite has a high degree of thermal stability, acid stability and selectivity. The catalytic properties of ZSM-5 can be improved by impregnating metals from the transition group, in this study using Ni (nickel). The results obtained that the catalyst Ni/ZSM-5 has a total acidity value of 0.920 mmol/g and has a specific surface area of 138.754 m 2 /g. The highest ethanol product was produced at 4 hours of sonication, which was 20.362%.
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