Devi Indrasari Mustopa Putri, S. Sumari, Handoko Darmokoesomo, G. Supriyanto, N. Nugroho
{"title":"超声与Ni/ZSM-5催化剂联合催化甘油制乙醇","authors":"Devi Indrasari Mustopa Putri, S. Sumari, Handoko Darmokoesomo, G. Supriyanto, N. Nugroho","doi":"10.31315/e.v20i1.8167","DOIUrl":null,"url":null,"abstract":": The increased production of biodiesel which is used as an alternative fuel has led to an increase in the by-product in the form of glycerol. This glycerol byproduct can be utilized by converting it into other compounds such as ethanol. The production of ethanol from glycerol requires a catalyst that can break down the molecular size of glycerol, one of which is zeolite. One type of zeolite that is good to use is ZSM-5, because this type of zeolite has a high degree of thermal stability, acid stability and selectivity. The catalytic properties of ZSM-5 can be improved by impregnating metals from the transition group, in this study using Ni (nickel). The results obtained that the catalyst Ni/ZSM-5 has a total acidity value of 0.920 mmol/g and has a specific surface area of 138.754 m 2 /g. The highest ethanol product was produced at 4 hours of sonication, which was 20.362%.","PeriodicalId":30703,"journal":{"name":"Eksergi","volume":" ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Conversion of Glycerol to Ethanol by Integrating Ultrasonic and Ni/ZSM-5 Catalyst\",\"authors\":\"Devi Indrasari Mustopa Putri, S. Sumari, Handoko Darmokoesomo, G. Supriyanto, N. Nugroho\",\"doi\":\"10.31315/e.v20i1.8167\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": The increased production of biodiesel which is used as an alternative fuel has led to an increase in the by-product in the form of glycerol. This glycerol byproduct can be utilized by converting it into other compounds such as ethanol. The production of ethanol from glycerol requires a catalyst that can break down the molecular size of glycerol, one of which is zeolite. One type of zeolite that is good to use is ZSM-5, because this type of zeolite has a high degree of thermal stability, acid stability and selectivity. The catalytic properties of ZSM-5 can be improved by impregnating metals from the transition group, in this study using Ni (nickel). The results obtained that the catalyst Ni/ZSM-5 has a total acidity value of 0.920 mmol/g and has a specific surface area of 138.754 m 2 /g. The highest ethanol product was produced at 4 hours of sonication, which was 20.362%.\",\"PeriodicalId\":30703,\"journal\":{\"name\":\"Eksergi\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-03-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Eksergi\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.31315/e.v20i1.8167\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Eksergi","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.31315/e.v20i1.8167","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Conversion of Glycerol to Ethanol by Integrating Ultrasonic and Ni/ZSM-5 Catalyst
: The increased production of biodiesel which is used as an alternative fuel has led to an increase in the by-product in the form of glycerol. This glycerol byproduct can be utilized by converting it into other compounds such as ethanol. The production of ethanol from glycerol requires a catalyst that can break down the molecular size of glycerol, one of which is zeolite. One type of zeolite that is good to use is ZSM-5, because this type of zeolite has a high degree of thermal stability, acid stability and selectivity. The catalytic properties of ZSM-5 can be improved by impregnating metals from the transition group, in this study using Ni (nickel). The results obtained that the catalyst Ni/ZSM-5 has a total acidity value of 0.920 mmol/g and has a specific surface area of 138.754 m 2 /g. The highest ethanol product was produced at 4 hours of sonication, which was 20.362%.