{"title":"用于光学器件制造的有机金属l-丙氨酸碘化镉晶体","authors":"Kathiravan Vaiyapuri , Thangavel Subramani , Ashok Kumar Rajamani , Muthu Lakshmi Thangavel , Satheesh Kumar Ganesan , Selvarajan Palanisamy , Kumaresavanji Malaivelusamy","doi":"10.1016/j.jnlest.2022.100178","DOIUrl":null,"url":null,"abstract":"<div><p>Single crystals of <span>l</span>-alanine cadmium iodide (LACI) were grown by adopting the slow evaporation technique at room temperature. A single-crystal X-ray diffraction (SXRD) model was used to evaluate the crystal structure of the as-grown LACI crystal. The energy dispersive X-ray (EDX) analysis and ultraviolet–visible–near infrared (UV-vis-NIR) transmittance studies were carried out, and the results reveal the presence of elements in the title compound. From the transmittance data, the optical bandgap as a function of photon energy was estimated, and the different optical constants were calculated. A fluorescence study was performed for the LACI crystal. Thermogravimetric and differential thermal analyses have also been studied to investigate the thermal property of the LACI crystal. The efficiency of the second harmonic generation (SHG) by the title crystal was investigated. The magnetic and electrical properties were estimated by the vibrating sample magnetometer (VSM) analysis and impedance study respectively.</p></div>","PeriodicalId":53467,"journal":{"name":"Journal of Electronic Science and Technology","volume":"20 4","pages":"Article 100178"},"PeriodicalIF":0.0000,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674862X22000313/pdfft?md5=c141dc2d24207e1fffe290a710389288&pid=1-s2.0-S1674862X22000313-main.pdf","citationCount":"1","resultStr":"{\"title\":\"Organometallic l-alanine cadmium iodide crystals for optical device fabrication\",\"authors\":\"Kathiravan Vaiyapuri , Thangavel Subramani , Ashok Kumar Rajamani , Muthu Lakshmi Thangavel , Satheesh Kumar Ganesan , Selvarajan Palanisamy , Kumaresavanji Malaivelusamy\",\"doi\":\"10.1016/j.jnlest.2022.100178\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Single crystals of <span>l</span>-alanine cadmium iodide (LACI) were grown by adopting the slow evaporation technique at room temperature. A single-crystal X-ray diffraction (SXRD) model was used to evaluate the crystal structure of the as-grown LACI crystal. The energy dispersive X-ray (EDX) analysis and ultraviolet–visible–near infrared (UV-vis-NIR) transmittance studies were carried out, and the results reveal the presence of elements in the title compound. From the transmittance data, the optical bandgap as a function of photon energy was estimated, and the different optical constants were calculated. A fluorescence study was performed for the LACI crystal. Thermogravimetric and differential thermal analyses have also been studied to investigate the thermal property of the LACI crystal. The efficiency of the second harmonic generation (SHG) by the title crystal was investigated. The magnetic and electrical properties were estimated by the vibrating sample magnetometer (VSM) analysis and impedance study respectively.</p></div>\",\"PeriodicalId\":53467,\"journal\":{\"name\":\"Journal of Electronic Science and Technology\",\"volume\":\"20 4\",\"pages\":\"Article 100178\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1674862X22000313/pdfft?md5=c141dc2d24207e1fffe290a710389288&pid=1-s2.0-S1674862X22000313-main.pdf\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electronic Science and Technology\",\"FirstCategoryId\":\"95\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1674862X22000313\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electronic Science and Technology","FirstCategoryId":"95","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1674862X22000313","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Engineering","Score":null,"Total":0}
Organometallic l-alanine cadmium iodide crystals for optical device fabrication
Single crystals of l-alanine cadmium iodide (LACI) were grown by adopting the slow evaporation technique at room temperature. A single-crystal X-ray diffraction (SXRD) model was used to evaluate the crystal structure of the as-grown LACI crystal. The energy dispersive X-ray (EDX) analysis and ultraviolet–visible–near infrared (UV-vis-NIR) transmittance studies were carried out, and the results reveal the presence of elements in the title compound. From the transmittance data, the optical bandgap as a function of photon energy was estimated, and the different optical constants were calculated. A fluorescence study was performed for the LACI crystal. Thermogravimetric and differential thermal analyses have also been studied to investigate the thermal property of the LACI crystal. The efficiency of the second harmonic generation (SHG) by the title crystal was investigated. The magnetic and electrical properties were estimated by the vibrating sample magnetometer (VSM) analysis and impedance study respectively.
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