过氧化苯甲酰和二乙烯基苯浓度对聚甲基丙烯酸缩水甘油酯- co -二乙烯基苯磁性微球性能的影响

IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL
Washington José Fernandes Formiga, Manoel Ribeiro da Silva, Henrique Almeida Cunha, Jacira Aparecida Castanharo, Ivana Lourenço de Mello de Ferreira, Marcos Antonio da Silva Costa
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引用次数: 0

摘要

本文报道了用悬浮聚合法制备聚甲基丙烯酸缩水甘油酯-共二乙烯基苯磁性微球。研究了合成微球时二乙烯基苯和过氧化苯甲酰的浓度。通过热分析、扫描电镜、振动样品磁强计和光散射检测对微球进行了表征,表明微球具有良好的形态控制和热稳定性。这种材料的尺寸范围窄,超顺磁性颗粒的比例相当可观。二乙烯基苯浓度的增加会导致微球的平均直径减小。另一方面,过氧化苯甲酰浓度的增加引起微球平均直径的增加。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Influence of Benzoyl Peroxide and Divinylbenzene Concentrations on the Properties of Poly(glycidyl methacrylate-co-divinylbenzene) Magnetic Microspheres

Influence of Benzoyl Peroxide and Divinylbenzene Concentrations on the Properties of Poly(glycidyl methacrylate-co-divinylbenzene) Magnetic Microspheres

In this work, the synthesis of magnetic microspheres of poly(glycidyl methacrylate-co-divinylbenzene) via suspension polymerization is reported. The concentrations of divinylbenzeneand benzoyl peroxide in the microspheres synthesis are studied. The microspheres, characterized by thermal analysis , scanning electron microscopy, vibrating sample magnetometry , and light scattering detection , show good morphological control and thermal stability. This material presents a narrow size range and an appreciable fraction of superparamagnetic particles. The increase in divinylbenzene concentration can cause a decrease in the mean diameter of the microspheres. On the other hand, the increase in benzoyl peroxide concentration causes an increase in the mean diameter of the microspheres.

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来源期刊
Macromolecular Reaction Engineering
Macromolecular Reaction Engineering 工程技术-高分子科学
CiteScore
2.60
自引率
20.00%
发文量
55
审稿时长
3 months
期刊介绍: Macromolecular Reaction Engineering is the established high-quality journal dedicated exclusively to academic and industrial research in the field of polymer reaction engineering.
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