Washington José Fernandes Formiga, Manoel Ribeiro da Silva, Henrique Almeida Cunha, Jacira Aparecida Castanharo, Ivana Lourenço de Mello de Ferreira, Marcos Antonio da Silva Costa
{"title":"过氧化苯甲酰和二乙烯基苯浓度对聚甲基丙烯酸缩水甘油酯- co -二乙烯基苯磁性微球性能的影响","authors":"Washington José Fernandes Formiga, Manoel Ribeiro da Silva, Henrique Almeida Cunha, Jacira Aparecida Castanharo, Ivana Lourenço de Mello de Ferreira, Marcos Antonio da Silva Costa","doi":"10.1002/mren.202200070","DOIUrl":null,"url":null,"abstract":"<p>In this work, the synthesis of magnetic microspheres of poly(glycidyl methacrylate-<i>co</i>-divinylbenzene) via suspension polymerization is reported. The concentrations of divinylbenzeneand benzoyl peroxide in the microspheres synthesis are studied. The microspheres, characterized by thermal analysis , scanning electron microscopy, vibrating sample magnetometry , and light scattering detection , show good morphological control and thermal stability. This material presents a narrow size range and an appreciable fraction of superparamagnetic particles. The increase in divinylbenzene concentration can cause a decrease in the mean diameter of the microspheres. On the other hand, the increase in benzoyl peroxide concentration causes an increase in the mean diameter of the microspheres.</p>","PeriodicalId":18052,"journal":{"name":"Macromolecular Reaction Engineering","volume":"17 4","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2023-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Benzoyl Peroxide and Divinylbenzene Concentrations on the Properties of Poly(glycidyl methacrylate-co-divinylbenzene) Magnetic Microspheres\",\"authors\":\"Washington José Fernandes Formiga, Manoel Ribeiro da Silva, Henrique Almeida Cunha, Jacira Aparecida Castanharo, Ivana Lourenço de Mello de Ferreira, Marcos Antonio da Silva Costa\",\"doi\":\"10.1002/mren.202200070\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this work, the synthesis of magnetic microspheres of poly(glycidyl methacrylate-<i>co</i>-divinylbenzene) via suspension polymerization is reported. The concentrations of divinylbenzeneand benzoyl peroxide in the microspheres synthesis are studied. The microspheres, characterized by thermal analysis , scanning electron microscopy, vibrating sample magnetometry , and light scattering detection , show good morphological control and thermal stability. This material presents a narrow size range and an appreciable fraction of superparamagnetic particles. The increase in divinylbenzene concentration can cause a decrease in the mean diameter of the microspheres. On the other hand, the increase in benzoyl peroxide concentration causes an increase in the mean diameter of the microspheres.</p>\",\"PeriodicalId\":18052,\"journal\":{\"name\":\"Macromolecular Reaction Engineering\",\"volume\":\"17 4\",\"pages\":\"\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2023-01-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Reaction Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/mren.202200070\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Reaction Engineering","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/mren.202200070","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Influence of Benzoyl Peroxide and Divinylbenzene Concentrations on the Properties of Poly(glycidyl methacrylate-co-divinylbenzene) Magnetic Microspheres
In this work, the synthesis of magnetic microspheres of poly(glycidyl methacrylate-co-divinylbenzene) via suspension polymerization is reported. The concentrations of divinylbenzeneand benzoyl peroxide in the microspheres synthesis are studied. The microspheres, characterized by thermal analysis , scanning electron microscopy, vibrating sample magnetometry , and light scattering detection , show good morphological control and thermal stability. This material presents a narrow size range and an appreciable fraction of superparamagnetic particles. The increase in divinylbenzene concentration can cause a decrease in the mean diameter of the microspheres. On the other hand, the increase in benzoyl peroxide concentration causes an increase in the mean diameter of the microspheres.
期刊介绍:
Macromolecular Reaction Engineering is the established high-quality journal dedicated exclusively to academic and industrial research in the field of polymer reaction engineering.