阴极溶出伏安法测定河水中金属Ni(II)的优化

H. Pardi, D. Fitriyah
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引用次数: 0

摘要

采用阴极溶出伏安法测定了河水中的金属镍。为了达到测定金属Ni(II)的最佳条件,实现了CSV法的积累电位和积累时间条件。本研究的结果是在使用氯化铵电解质溶液测量Ni(II)的最佳条件下获得的,该电解质溶液的电位累积(accv)为-0.7V,时间累积(acct)为60s。10µg/L Ni(Ⅱ)标准溶液(n=8)的相对标准偏差为0.53%,回收率为98.82%。CSV法已成功应用于河水样品中金属镍的测定。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optimisation of The Cathodic Stripping Voltammetry For The Determination of Metal Ni(II) in The River Water
The study was carried out to determination the metal Ni(II) in river water samples using cathodic stripping voltammetry (CSV) method. In order to achieve optimum conditions for the determination of metal Ni(II), the accumulation potential and accumulation time conditions of the CSV method have been achieved. The results of this research obtained under the optimum conditions for Ni(II) measurement using an electrolyte solution of ammonium chloride with a potential accumulation (accv) of -0.7 V and a time accumulation (acct) of 60 s. The relative standard deviation of the 10 µg/L Ni(II) standard solution (n=8) is 0.53%, the recovery value is 98.82%. The CSV method for the determination of Ni(II) metal has been successfully applied to river water samples.
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