{"title":"钨离子对磷酸砷铅玻璃结构、弹性模量和屏蔽特性的影响","authors":"B. Basha, K. Shaaban, E. A. Abdel Wahab","doi":"10.15251/djnb.2023.182.713","DOIUrl":null,"url":null,"abstract":"A series of phosphate glass with the following formulation was manufactured using the melt quenching procedure: 3As2O3 – 37PbO – (60 − 𝑥𝑥) P2O5- 𝑥𝑥 WO3, 𝑥𝑥 = (0 ≤ 𝑥𝑥 ≤ 5 mol. %). The glasses' physical and other structural characteristics were examined in depth. The basic structural properties of the materials were examined using a variety of characterization procedures, such as XRD and FT-IR. With increasing WO3 concentration, the phosphate network evolves, leading to depolymerization of the glass network, according to the FT-IR analysis. With increasing WO3, the physical, mechanical, and structural parameters were enhanced like glass density, longitudinal and shear speeds, and all elastic moduli. Because of P–O–W bonds in the glass network are stronger than P–O– P bonds, the radiation characteristics were enhanced as the content of WO3 increased. The interpretation of the parameters showed that the glass in the statement is an excellent candidate for photon shielding applications.","PeriodicalId":11233,"journal":{"name":"Digest Journal of Nanomaterials and Biostructures","volume":" ","pages":""},"PeriodicalIF":1.0000,"publicationDate":"2023-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The effect of tungsten ions on the structural, elastic moduli, and shielding characteristics of arsenic lead phosphate glasses\",\"authors\":\"B. Basha, K. Shaaban, E. A. Abdel Wahab\",\"doi\":\"10.15251/djnb.2023.182.713\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A series of phosphate glass with the following formulation was manufactured using the melt quenching procedure: 3As2O3 – 37PbO – (60 − 𝑥𝑥) P2O5- 𝑥𝑥 WO3, 𝑥𝑥 = (0 ≤ 𝑥𝑥 ≤ 5 mol. %). The glasses' physical and other structural characteristics were examined in depth. The basic structural properties of the materials were examined using a variety of characterization procedures, such as XRD and FT-IR. With increasing WO3 concentration, the phosphate network evolves, leading to depolymerization of the glass network, according to the FT-IR analysis. With increasing WO3, the physical, mechanical, and structural parameters were enhanced like glass density, longitudinal and shear speeds, and all elastic moduli. Because of P–O–W bonds in the glass network are stronger than P–O– P bonds, the radiation characteristics were enhanced as the content of WO3 increased. The interpretation of the parameters showed that the glass in the statement is an excellent candidate for photon shielding applications.\",\"PeriodicalId\":11233,\"journal\":{\"name\":\"Digest Journal of Nanomaterials and Biostructures\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2023-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Digest Journal of Nanomaterials and Biostructures\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.15251/djnb.2023.182.713\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Digest Journal of Nanomaterials and Biostructures","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.15251/djnb.2023.182.713","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
一系列磷酸盐玻璃具有以下配方是生产使用熔体淬火过程:3 as2o3 - 37 pbo(60−𝑥𝑥)P2O5——𝑥𝑥WO3,𝑥𝑥=(0≤𝑥𝑥≤5摩尔。%)。对玻璃的物理和其他结构特性进行了深入的研究。采用XRD和FT-IR等多种表征手段对材料的基本结构性能进行了表征。根据FT-IR分析,随着WO3浓度的增加,磷酸盐网络演变,导致玻璃网络解聚。随着WO3的增加,玻璃密度、纵向和剪切速度以及所有弹性模量等物理、机械和结构参数都得到了增强。由于玻璃网络中的P - o - w键比P - o - P键更强,因此随着WO3含量的增加,辐射特性增强。对参数的解释表明,声明中的玻璃是光子屏蔽应用的理想候选者。
The effect of tungsten ions on the structural, elastic moduli, and shielding characteristics of arsenic lead phosphate glasses
A series of phosphate glass with the following formulation was manufactured using the melt quenching procedure: 3As2O3 – 37PbO – (60 − 𝑥𝑥) P2O5- 𝑥𝑥 WO3, 𝑥𝑥 = (0 ≤ 𝑥𝑥 ≤ 5 mol. %). The glasses' physical and other structural characteristics were examined in depth. The basic structural properties of the materials were examined using a variety of characterization procedures, such as XRD and FT-IR. With increasing WO3 concentration, the phosphate network evolves, leading to depolymerization of the glass network, according to the FT-IR analysis. With increasing WO3, the physical, mechanical, and structural parameters were enhanced like glass density, longitudinal and shear speeds, and all elastic moduli. Because of P–O–W bonds in the glass network are stronger than P–O– P bonds, the radiation characteristics were enhanced as the content of WO3 increased. The interpretation of the parameters showed that the glass in the statement is an excellent candidate for photon shielding applications.