TPU-based porous heterostructures by combined techniques

Abstract The production of thermoplastic polyurethane-based porous heterostructures combining physical foaming with fused deposition modeling is detailed in this contribution. The choice of combining these two techniques lies in the possibility of creating objects endowed with a dual-scale structure at millimeter scale by fused deposition modeling and at microscopic scale by gas foaming. Thermal stability and rheological properties of the neat polymer were studied prior to foaming to design a suitable processing protocol and three different combined techniques are proposed: pressure quench, temperature rise and direct 3D foam printing. Foam morphologies were evaluated by SEM and foamed samples were characterized by thermal and mechanical analyses to highlight the differences among the combined processing techniques. Samples foamed via pressure quench exhibit the highest degree of crystallinity and a uniform cell morphology, also resulting in the largest stiffness. The results presented in this contribution open up the possibility of producing objects with complex geometry and porosity architecture at the dual scale.