基于PbO2制备纳米复合负极材料的新途径

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Theoretical and Experimental Chemistry Pub Date : 2022-02-11 DOI:10.1007/s11237-022-09709-6

A. B. Velichenko, T. V. Luk’yanenko, O. B. Shmychkova, V. O. Knysh

{"title":"基于PbO2制备纳米复合负极材料的新途径","authors":"A. B. Velichenko, T. V. Luk’yanenko, O. B. Shmychkova, V. O. Knysh","doi":"10.1007/s11237-022-09709-6","DOIUrl":null,"url":null,"abstract":"<div><div><p>An original approach to the creation of new nanocomposite anode materials based on PbO<sub>2</sub> and to the processes of composite formation due to the influence of selective adsorption of valve metal oxides and different types of surfactants on both electrochemical and colloid-chemical processes in the near-electrode zone is considered. It is shown that variation of deposition electrolyte composition, current density, and temperature allows one to change the content of additives in composites and to provide control of morphology, texture, phase composition, physicochemical properties, electrocatalytic activity, and selectivity of electrocatalysts based on PbO<sub>2</sub> in target processes.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2022-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"New Approaches to the Creation of Nanocomposite Anode Materials Based on PbO2: A Review\",\"authors\":\"A. B. Velichenko, T. V. Luk’yanenko, O. B. Shmychkova, V. O. Knysh\",\"doi\":\"10.1007/s11237-022-09709-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>An original approach to the creation of new nanocomposite anode materials based on PbO<sub>2</sub> and to the processes of composite formation due to the influence of selective adsorption of valve metal oxides and different types of surfactants on both electrochemical and colloid-chemical processes in the near-electrode zone is considered. It is shown that variation of deposition electrolyte composition, current density, and temperature allows one to change the content of additives in composites and to provide control of morphology, texture, phase composition, physicochemical properties, electrocatalytic activity, and selectivity of electrocatalysts based on PbO<sub>2</sub> in target processes.</p></div></div>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2022-02-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-022-09709-6\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-022-09709-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 2

摘要

本文考虑了一种基于PbO2的新型纳米复合阳极材料的创建方法，以及由于阀门金属氧化物和不同类型表面活性剂对近电极区电化学和胶体化学过程的选择性吸附的影响而形成复合材料的过程。研究表明，通过改变沉积电解质组成、电流密度和温度，可以改变复合材料中添加剂的含量，从而控制基于PbO2的电催化剂在目标过程中的形貌、织体、相组成、理化性质、电催化活性和选择性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

New Approaches to the Creation of Nanocomposite Anode Materials Based on PbO2: A Review

An original approach to the creation of new nanocomposite anode materials based on PbO₂ and to the processes of composite formation due to the influence of selective adsorption of valve metal oxides and different types of surfactants on both electrochemical and colloid-chemical processes in the near-electrode zone is considered. It is shown that variation of deposition electrolyte composition, current density, and temperature allows one to change the content of additives in composites and to provide control of morphology, texture, phase composition, physicochemical properties, electrocatalytic activity, and selectivity of electrocatalysts based on PbO₂ in target processes.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.60

自引率

10.00%

发文量

审稿时长

6-12 weeks

期刊介绍： Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.