油酸碱性皂热解生产生物汽油

IF 0.9 Q3 ENGINEERING, MULTIDISCIPLINARY

Journal of Engineering and Technological Sciences Pub Date : 2022-05-31 DOI:10.5614/j.eng.technol.sci.2022.54.3.11

E. Puspawiningtiyas, T. Prakoso, M. Pratiwi, S. Subagjo, T. Soerawidjaja

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引用次数: 1

摘要

本文研究了Ca/Mg/Zn混合比对油基皂热解制汽油级烃的影响。在锌含量不变的情况下，钙镁用量分别为15%、35%、50%、65%和85%。采用改进的熔融法制备油基皂。热解实验在450℃半连续反应器中进行，进料流量为5 g/15 min。热解过程产生气、固、液(生物烃+水)三组分。气相色谱- tcd对产物进行了表征，结果表明产物中存在二氧化碳、氢、氮、氧和甲烷。GC-FID和FT-IR结果表明，生物烃主要由碳数为C7 ~ C19的同源烃类组成，含正构烷烃、烯烃、各种异构烷烃和一些含氧化合物。油基皂中各钙比均以汽油(c7 ~ c11)为主导产物。当钙含量为15%时，汽油收率最高，为74.86%。

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Production of Biogasoline via Pyrolysis of Oleic Acid Basic Soaps

In this study, an investigation on the effect of the Ca/Mg/Zn mixing ratio on gasoline-range hydrocarbon production by oleic basic soap pyrolysis was carried out. The ratios of calcium to magnesium used were 15%, 35%, 50%, 65%, and 85% with constant Zn. Oleic basic soap was obtained by saponification with the modified fusion method. Pyrolysis experiments were carried out at 450 °C using a semi-continuous reactor with a feed flow rate of 5 g/15 min. The process produced three fractions, i.e., gas, solid, and liquid (bio-hydrocarbon + water). The gas products were characterized by GC-TCD, and the results showed the presence of carbon dioxide, hydrogen, nitrogen, oxygen, and methane. Based on the GC-FID and FT-IR results, the bio-hydrocarbon comprised mainly homologous hydrocarbon from carbon number C7 to C19 containing n-alkanes, alkenes, various iso-alkanes, and some oxygenated compounds. All calcium ratios in the oleic basic soap produced hydrocarbon in the range of gasoline (C7-C11) as the dominant product. The maximum yield of gasoline (74.86%) was achieved at 15% calcium.

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来源期刊

Journal of Engineering and Technological Sciences ENGINEERING, MULTIDISCIPLINARY-

CiteScore

2.30

自引率

11.10%

发文量

审稿时长

24 weeks

期刊介绍： Journal of Engineering and Technological Sciences welcomes full research articles in the area of Engineering Sciences from the following subject areas: Aerospace Engineering, Biotechnology, Chemical Engineering, Civil Engineering, Electrical Engineering, Engineering Physics, Environmental Engineering, Industrial Engineering, Information Engineering, Mechanical Engineering, Material Science and Engineering, Manufacturing Processes, Microelectronics, Mining Engineering, Petroleum Engineering, and other application of physical, biological, chemical and mathematical sciences in engineering. Authors are invited to submit articles that have not been published previously and are not under consideration elsewhere.