超声波快速有效合成硼酸钾：Santite

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Main Group Metal Chemistry Pub Date : 2022-01-01 DOI:10.1515/mgmc-2022-0004

Sibel Ila, A. Kipcak, E. Derun

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引用次数: 0

摘要

摘要以K2CO3、KNO3、NaOH、H3BO3、B2O3、Na2B4O9·5H2O和Na2B4O9·10H2O为原料，在60℃、70℃、80℃和90℃的反应温度下，反应时间分别为2.5、5、10和15 min，合成了硼酸钾桑提岩化合物。根据x射线衍射分析，合成的硼酸钾化合物鉴定为“桑蒂石(KB5O8·4H2O)”，粉末衍射锉号为。01-072-1688。拉曼光谱结果表明，合成的化合物由典型的硼矿物谱带组成，所得光谱与文献所述硼酸钾相一致。扫描电镜形貌显示，随着原料组合的变化，制备的斜晶石具有不同的颗粒形状，粒径分布在305 nm ~ 2.03µm之间。总的反应产率在76.11% ~ 99.26%之间，与文献相比反应时间更短。

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Ultra-fast and effective ultrasonic synthesis of potassium borate: Santite

Abstract In this study, a potassium borate compound of santite is synthesized at 60°C, 70°C, 80°C, and 90°C reaction temperature for 2.5, 5, 10, and 15 min reaction time by using eight different raw material combinations of K2CO3, KNO3, NaOH, H3BO3, B2O3, Na2B4O9·5H2O, and Na2B4O9·10H2O. According to the X-ray diffraction analysis synthesized potassium borate compound is identified as “santite (KB5O8·4H2O)” with powder diffraction file no. 01-072-1688. Raman spectroscopy results showed that the synthesized compound consists of typical boron mineral bands, and the spectra obtained were in mutual agreement with potassium borate, according to the literature. Scanning electron microscopic morphologies showed that obtained santite has different particle shapes as the raw material combination changed and the particle sizes are found between 305 nm and 2.03 µm. Overall reaction yields are found between 76.11% and 99.26%, even such lower reaction times with respect to the literature.

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来源期刊

Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC

CiteScore

4.10

自引率

27.80%

发文量

审稿时长

4 weeks

期刊介绍： This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.