{"title":"四臂星形聚合物形成的临界聚合物团簇的结构和动力学","authors":"Xiang Li","doi":"10.1678/rheology.50.113","DOIUrl":null,"url":null,"abstract":"Critical polymer clusters are massive randomly branched polymers formed near the gelation threshold. Because of their universal physical properties, such as the size distribution, mass fractal dimension, and viscoelastic properties, these clusters have drawn the great attention of many physicists. This review briefly introduces a few recent remarkable experimental results, which shed light on remaining questions of the critical clusters. The static structure and dynamics of these critical clusters were investigated using small angle neutron scattering (SANS), static light scattering (SLS), and dynamic light scattering (DLS). The reviewed studies primarily focused on the data analysis for the critical clusters in the intermediate concentrations between dilute and semidilute limits. An intermediate model developed by Bastide and Candau well ex-plained the observed static scattering profiles, indicating a coexisting state of the dilute and semidilute solutions. The dilute and semidilute features were also observed in dynamic studies as a superimposed translational motion of small dilute clusters and cooperatively diffusion of large semidilute clusters. These fundamental understanding may contribute to the applications of the critical clusters and further studies for the percolation process.","PeriodicalId":19282,"journal":{"name":"Nihon Reoroji Gakkaishi","volume":" ","pages":""},"PeriodicalIF":1.3000,"publicationDate":"2022-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structure and Dynamics of Critical Polymer Clusters Formed with Tetra-Armed Star-Polymers\",\"authors\":\"Xiang Li\",\"doi\":\"10.1678/rheology.50.113\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Critical polymer clusters are massive randomly branched polymers formed near the gelation threshold. Because of their universal physical properties, such as the size distribution, mass fractal dimension, and viscoelastic properties, these clusters have drawn the great attention of many physicists. This review briefly introduces a few recent remarkable experimental results, which shed light on remaining questions of the critical clusters. The static structure and dynamics of these critical clusters were investigated using small angle neutron scattering (SANS), static light scattering (SLS), and dynamic light scattering (DLS). The reviewed studies primarily focused on the data analysis for the critical clusters in the intermediate concentrations between dilute and semidilute limits. An intermediate model developed by Bastide and Candau well ex-plained the observed static scattering profiles, indicating a coexisting state of the dilute and semidilute solutions. The dilute and semidilute features were also observed in dynamic studies as a superimposed translational motion of small dilute clusters and cooperatively diffusion of large semidilute clusters. These fundamental understanding may contribute to the applications of the critical clusters and further studies for the percolation process.\",\"PeriodicalId\":19282,\"journal\":{\"name\":\"Nihon Reoroji Gakkaishi\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2022-02-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nihon Reoroji Gakkaishi\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1678/rheology.50.113\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MECHANICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nihon Reoroji Gakkaishi","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1678/rheology.50.113","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MECHANICS","Score":null,"Total":0}
Structure and Dynamics of Critical Polymer Clusters Formed with Tetra-Armed Star-Polymers
Critical polymer clusters are massive randomly branched polymers formed near the gelation threshold. Because of their universal physical properties, such as the size distribution, mass fractal dimension, and viscoelastic properties, these clusters have drawn the great attention of many physicists. This review briefly introduces a few recent remarkable experimental results, which shed light on remaining questions of the critical clusters. The static structure and dynamics of these critical clusters were investigated using small angle neutron scattering (SANS), static light scattering (SLS), and dynamic light scattering (DLS). The reviewed studies primarily focused on the data analysis for the critical clusters in the intermediate concentrations between dilute and semidilute limits. An intermediate model developed by Bastide and Candau well ex-plained the observed static scattering profiles, indicating a coexisting state of the dilute and semidilute solutions. The dilute and semidilute features were also observed in dynamic studies as a superimposed translational motion of small dilute clusters and cooperatively diffusion of large semidilute clusters. These fundamental understanding may contribute to the applications of the critical clusters and further studies for the percolation process.
期刊介绍:
For the communication among the members, the journal of the Society of Rheology Japan, NIHON REOROJI GAKKAISHI (5 issues per year), was established in 1973 and it is the oldest journal on rheology in Asia. The journal contains original and review articles on rheology and related topics, information for all SRJ events, and reports of domestic/overseas meetings. Articles in Japanese as well as in English are considered for publication, not only from the members but also from the researchers outside. Papers from new emerging areas of the field are particularly welcome. The electronic version of the articles is available via the internet with an open access policy.