{"title":"Co含量对Al0.3CoxCrFeNi高熵合金组织及腐蚀行为的影响","authors":"Zequn Zhang, Qijuan Dong, Zhibin Chen, Junsheng Wu, Jiuyang Xia, Kang Huang, Pengcheng Zuo, Wei Xue, Bowei Zhang","doi":"10.1007/s12540-023-01513-8","DOIUrl":null,"url":null,"abstract":"<div><p>The influence of Co content on the microstructure and corrosion behavior of Al<sub>0.3</sub>Co<sub>x</sub>CrFeNi (x = 0.25, 0.5 and 1.0) high entropy alloys were investigated. The results indicated that the increased content of Co improve the corrosion resistance of alloy, which can be attributed to the distinction of phase composition in alloys caused by different Co content. The Al<sub>0.3</sub>Co<sub>x</sub>CrFeNi alloy shows a double-phase (FCC + BCC) structure for x = 0.25 and 0.5, and BCC phase consists of (Al, Ni)-rich B2 phase and (Cr, Fe, Co)-rich A2 phase. The increase of Co content induces the transformations of crystal-structures from BCC to FCC, resulting in the decrease of BCC phase proportion. The Al<sub>0.3</sub>CoCrFeNi alloy exhibits the single FCC structure, and all elements tend to be homogeneously distributed. The difference in the potential of FCC and BCC phases indicates the BCC phase acts as anode resulting to localized corrosion, while B2 phase preferentially dissolves compared to the A2 phase due to the lower potential. Therefore, the existence of selective corrosion is found in the alloys with double-phase, by contrast, the alloy with single FCC phase shows random pitting corrosion.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":703,"journal":{"name":"Metals and Materials International","volume":"30 2","pages":"360 - 369"},"PeriodicalIF":3.3000,"publicationDate":"2023-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Co Content on the Microstructure and Corrosion Behavior of Al0.3CoxCrFeNi High Entropy Alloys\",\"authors\":\"Zequn Zhang, Qijuan Dong, Zhibin Chen, Junsheng Wu, Jiuyang Xia, Kang Huang, Pengcheng Zuo, Wei Xue, Bowei Zhang\",\"doi\":\"10.1007/s12540-023-01513-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The influence of Co content on the microstructure and corrosion behavior of Al<sub>0.3</sub>Co<sub>x</sub>CrFeNi (x = 0.25, 0.5 and 1.0) high entropy alloys were investigated. The results indicated that the increased content of Co improve the corrosion resistance of alloy, which can be attributed to the distinction of phase composition in alloys caused by different Co content. The Al<sub>0.3</sub>Co<sub>x</sub>CrFeNi alloy shows a double-phase (FCC + BCC) structure for x = 0.25 and 0.5, and BCC phase consists of (Al, Ni)-rich B2 phase and (Cr, Fe, Co)-rich A2 phase. The increase of Co content induces the transformations of crystal-structures from BCC to FCC, resulting in the decrease of BCC phase proportion. The Al<sub>0.3</sub>CoCrFeNi alloy exhibits the single FCC structure, and all elements tend to be homogeneously distributed. The difference in the potential of FCC and BCC phases indicates the BCC phase acts as anode resulting to localized corrosion, while B2 phase preferentially dissolves compared to the A2 phase due to the lower potential. Therefore, the existence of selective corrosion is found in the alloys with double-phase, by contrast, the alloy with single FCC phase shows random pitting corrosion.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":703,\"journal\":{\"name\":\"Metals and Materials International\",\"volume\":\"30 2\",\"pages\":\"360 - 369\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2023-08-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Metals and Materials International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12540-023-01513-8\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Metals and Materials International","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s12540-023-01513-8","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Effect of Co Content on the Microstructure and Corrosion Behavior of Al0.3CoxCrFeNi High Entropy Alloys
The influence of Co content on the microstructure and corrosion behavior of Al0.3CoxCrFeNi (x = 0.25, 0.5 and 1.0) high entropy alloys were investigated. The results indicated that the increased content of Co improve the corrosion resistance of alloy, which can be attributed to the distinction of phase composition in alloys caused by different Co content. The Al0.3CoxCrFeNi alloy shows a double-phase (FCC + BCC) structure for x = 0.25 and 0.5, and BCC phase consists of (Al, Ni)-rich B2 phase and (Cr, Fe, Co)-rich A2 phase. The increase of Co content induces the transformations of crystal-structures from BCC to FCC, resulting in the decrease of BCC phase proportion. The Al0.3CoCrFeNi alloy exhibits the single FCC structure, and all elements tend to be homogeneously distributed. The difference in the potential of FCC and BCC phases indicates the BCC phase acts as anode resulting to localized corrosion, while B2 phase preferentially dissolves compared to the A2 phase due to the lower potential. Therefore, the existence of selective corrosion is found in the alloys with double-phase, by contrast, the alloy with single FCC phase shows random pitting corrosion.
期刊介绍：
Metals and Materials International publishes original papers and occasional critical reviews on all aspects of research and technology in materials engineering: physical metallurgy, materials science, and processing of metals and other materials. Emphasis is placed on those aspects of the science of materials that are concerned with the relationships among the processing, structure and properties (mechanical, chemical, electrical, electrochemical, magnetic and optical) of materials. Aspects of processing include the melting, casting, and fabrication with the thermodynamics, kinetics and modeling.
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