利用碘化铋铯研究玻璃中铯的化学分析新技术评价

IF 1.5 4区材料科学 Q3 MATERIALS SCIENCE, CERAMICS

Transactions of the Indian Ceramic Society Pub Date : 2023-07-03 DOI:10.1080/0371750X.2023.2212002

Bibhas Kumar, Biplab Das, P. Sinha, U. Jain, P. Sengupta, A. K. Mandal

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引用次数: 0

摘要

目前的工作旨在定性调查铯含量存在于一个玻璃。在常规加热炉中制备了由(wt%) Cs2O(30)-SiO2(35)-Na2O(7)-SnO2(4)- zno(24)组成的玻璃。采用Dragendorff试剂对玻璃样品中的铯含量进行重量分析，形成Cs3Bi2I9晶体(盐)。研究了提纯盐类的实验方法。采用FESEM-EDX和XRD对Cs3Bi2I9晶体进行定性分析。可以合成纯度高达~ 93%的Cs3Bi2I9。定量研究是用含有不同铯成分的Cs2CO3配制的标准铯溶液在1000至3000 ppm范围内进行的。得出的结论是，产生的盐的重量与玻璃溶液中存在的铯含量密切相关。图形抽象

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Assessment of a Novel Chemical Analysis Technique to Investigate Cesium in Glass by Developing Cesium Bismuth Iodide

The present work aims at qualitative investigation of cesium content present in a glass. A glass comprising (wt%) Cs2O(30)-SiO2(35)-Na2O(7)-SnO2(4)-Z nO(24) was prepared in a conventional heating furnace. A novel method was developed adopting gravimetric analysis of cesium content in the glass samples using Dragendorff’s reagent, leading to formation of Cs3Bi2I9 crystal (salt). Experimental methods were examined to purify the salt. Qualitative analysis was performed on Cs3Bi2I9 crystal with FESEM-EDX and XRD. Up to ∼93% pure Cs3Bi2I9 could be synthesized. Quantitative studies were performed with standard cesium solution prepared with Cs2CO3 with varying compositions of cesium within 1000 to 3000 ppm. Weight of salt produced was concluded to be strongly related to the cesium content present in the glass solution. GRAPHICAL ABSTRACT

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来源期刊

Transactions of the Indian Ceramic Society 工程技术-材料科学：硅酸盐

CiteScore

2.40

自引率

8.30%

发文量

审稿时长

2.3 months

期刊介绍： Transactions of the Indian Ceramic Society is a quarterly Journal devoted to current scientific research, technology and industry-related news on glass and ceramics. The Journal covers subjects such as the chemical, mechanical, optical, electronic and spectroscopic properties of glass and ceramics, and characterization of materials belonging to this family. The Editor invites original research papers, topical reviews, opinions and achievements, as well as industry profiles for publication. The contributions should be accompanied by abstracts, keywords and other details, as outlined in the Instructions for Authors section. News, views and other comments on activities of specific industries and organizations, and also analyses of industrial scenarios are also welcome.