ZnBTC基MOFs的合成与表征：溶剂和盐的影响

Q4 Materials Science

Chimica Techno Acta Pub Date : 2022-12-22 DOI:10.15826/chimtech.2023.10.1.05

M. Timofeeva, Andrey N. Yankin

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引用次数: 0

摘要

在这项工作中，我们研究了在各种合成条件下创建结构修饰的金属有机框架的合成方法的优化。我们研究了各种溶剂和锌盐对基于苯-1，3，5-三羧酸（H3BTC）的金属有机骨架结构特征的影响。结果表明，溶剂和盐类型的变化是影响金属有机骨架结晶度、相纯度和形态的一个参数。综合结构表征（SEM、EDX、PXRD）证实了这一点。

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Synthesis and characterization of ZnBTC-based MOFs: effect of solvents and salt

In this work, we studied the optimization of synthetic approaches to creating structurally modified metal-organic frameworks under various synthesis conditions. We investigated the influence of the various solvents and zinc salts on the structural characteristics of the metal-organic framework based on benzene-1,3,5-tricarboxylic acid (H3BTC). The results indicate that the variation of the types of both solvent and salt is a parameter affecting the crystallinity, phase purity, and morphology of the metal-organic framework. This was confirmed by comprehensive structural characterization (SEM, EDX, PXRD).

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来源期刊

Chimica Techno Acta Chemical Engineering-Chemical Engineering (all)

CiteScore

1.00

自引率

0.00%

发文量

审稿时长

4 weeks