棕榈仁壳活性炭在生物柴油生产中的催化作用

Erna Astuti, Z. Mufrodi, G. Budiarti, Ayu Citra Dewi, Mar'atul Husna
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引用次数: 1

摘要

棕榈仁壳是棕榈油加工的主要废弃物之一。棕榈仁壳是可以用作生物柴油生产催化剂的废物。除了许多天然成分外,与其他催化剂相比,由这些材料制备的催化剂的价格也相对便宜,使生物柴油的生产更加可持续和环保。本研究旨在以棕榈壳为原料,通过炭化和化学活化的方法制备活性炭。碳化过程在550℃下进行3小时,直到形成木炭。而活化过程是使用浓度为0.1M、0.25M、0.5M和1M的ZnCl2活化剂进行的,这些活化剂在90℃下活化4小时。根据FTIR分析的结果,O-H和C-O键的存在表明棕榈果壳产生的碳倾向于极性(挥发性)。因此,所生产的木炭可以用作生物柴油生产中的催化剂。对于SEM测试结果,从形态学上可以看出,添加了更多的孔晶体,并且在0.1M的ZnCl2浓度下仍然是脆性的。基于FTIR和SEM分析,最好的活性炭是浓度为0.25M ZnCl2的活性炭。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Active Charcoal from Palm Kernel Shells as a Catalyst in The Production of Biodiesel
Palm kernel shells are one of the main wastes for processing of palm oil. Palm kernel shells are waste that can be used as a catalyst in the biodiesel production. Besides many natural ingredients, the price of catalyst prepared from these materials is also relatively cheap compared to other catalysts, make the biodiesel production more sustainable, and environmentally friendly. This study aims to make activated carbon from palm shell through the process of carbonization and chemical activation. The carbonization process was carried out at 550oC for 3 hours until charcoal was formed. While the activation process was carried out using ZnCl2 activators with concentrations of 0.1 M, 0.25 M, 0.5 M and 1 M which were activated for 4 hours at 90oC.  Based on the results of the FTIR analysis the presence of O-H and C-O bonds indicates that the carbon produced from the palm kernel shell tends to be polar (volatile). Thus the charcoal produced can be used as catalyst in the biodiesel production. For the SEM test results, it can be seen morphologically that more pore crystals are added and are still brittle at a ZnCl2 concentration of 0.1 M. Based on FTIR and SEM analysis, the best activated charcoal was activated charcoal with a concentration of 0.25 M ZnCl2.
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