{"title":"用于气体反应的金属有机框架衍生的集成电催化剂","authors":"Yuke Song, Wenfu Xie, Mingfei Shao, Xue Duan","doi":"10.1016/j.nanoms.2022.01.003","DOIUrl":null,"url":null,"abstract":"<div><p>Integrated electrocatalysts (IECs) containing well-defined functional materials directly grown on the current collector have sparked increasing interest in the fields of electrocatalysis owing to efficient activity, high stability and the fact that they are easily assembled into devices. Recently, metal organic frameworks (MOFs) provide a promising platform for constructing advanced IECs because of their properties of low cost, large surface area and efficient structural tunability. In this review, the design principles of state-of-the-art IECs based on MOFs are presented, including by hydrothermal/solvothermal, template-directed, electrospinning, electrodeposition and other methods. The high performance of MOF-derived IECs has also been demonstrated in electrocatalytic gas-involved reactions. This is promising for green energy storage and conversion. The structure-activity relationship and performance improvement mechanism of IECs are uncovered by discussing some <em>in situ</em> technologies for IECs. Finally, we provide an outlook on the challenges and prospects in this booming field.</p></div>","PeriodicalId":33573,"journal":{"name":"Nano Materials Science","volume":"5 2","pages":"Pages 161-176"},"PeriodicalIF":9.9000,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"Integrated electrocatalysts derived from metal organic frameworks for gas-involved reactions\",\"authors\":\"Yuke Song, Wenfu Xie, Mingfei Shao, Xue Duan\",\"doi\":\"10.1016/j.nanoms.2022.01.003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Integrated electrocatalysts (IECs) containing well-defined functional materials directly grown on the current collector have sparked increasing interest in the fields of electrocatalysis owing to efficient activity, high stability and the fact that they are easily assembled into devices. Recently, metal organic frameworks (MOFs) provide a promising platform for constructing advanced IECs because of their properties of low cost, large surface area and efficient structural tunability. In this review, the design principles of state-of-the-art IECs based on MOFs are presented, including by hydrothermal/solvothermal, template-directed, electrospinning, electrodeposition and other methods. The high performance of MOF-derived IECs has also been demonstrated in electrocatalytic gas-involved reactions. This is promising for green energy storage and conversion. The structure-activity relationship and performance improvement mechanism of IECs are uncovered by discussing some <em>in situ</em> technologies for IECs. Finally, we provide an outlook on the challenges and prospects in this booming field.</p></div>\",\"PeriodicalId\":33573,\"journal\":{\"name\":\"Nano Materials Science\",\"volume\":\"5 2\",\"pages\":\"Pages 161-176\"},\"PeriodicalIF\":9.9000,\"publicationDate\":\"2023-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano Materials Science\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2589965122000034\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano Materials Science","FirstCategoryId":"1089","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2589965122000034","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Engineering","Score":null,"Total":0}
Integrated electrocatalysts derived from metal organic frameworks for gas-involved reactions
Integrated electrocatalysts (IECs) containing well-defined functional materials directly grown on the current collector have sparked increasing interest in the fields of electrocatalysis owing to efficient activity, high stability and the fact that they are easily assembled into devices. Recently, metal organic frameworks (MOFs) provide a promising platform for constructing advanced IECs because of their properties of low cost, large surface area and efficient structural tunability. In this review, the design principles of state-of-the-art IECs based on MOFs are presented, including by hydrothermal/solvothermal, template-directed, electrospinning, electrodeposition and other methods. The high performance of MOF-derived IECs has also been demonstrated in electrocatalytic gas-involved reactions. This is promising for green energy storage and conversion. The structure-activity relationship and performance improvement mechanism of IECs are uncovered by discussing some in situ technologies for IECs. Finally, we provide an outlook on the challenges and prospects in this booming field.
期刊介绍:
Nano Materials Science (NMS) is an international and interdisciplinary, open access, scholarly journal. NMS publishes peer-reviewed original articles and reviews on nanoscale material science and nanometer devices, with topics encompassing preparation and processing; high-throughput characterization; material performance evaluation and application of material characteristics such as the microstructure and properties of one-dimensional, two-dimensional, and three-dimensional nanostructured and nanofunctional materials; design, preparation, and processing techniques; and performance evaluation technology and nanometer device applications.