高介电常数、低介电损耗的聚烯烃/石墨烯纳米复合材料的研究进展

Q3 Materials Science
H. Aldosari, N. Madkhali, Saja Algasser, M. Khairy
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引用次数: 0

摘要

氧化石墨烯(GO)中附着的氧官能团厚度约为1.1±0.2 nm,阻碍了其电学特性的表现。减少氧官能团,提高碳氧比(C/O),可以提高导电性能。本研究考察了石墨烯衍生物(C/O)比对茂金属低密度聚乙烯(PE)、聚丙烯(PP)及其混合物介电性能的影响。利用氧化石墨烯(GO)和还原氧化石墨烯(rGO)还原氧官能团。探讨了降低氧官能团的溶液共混法制备氧化石墨烯和rgo基聚烯烃的效果。利用扫描电子显微镜(SEM)和傅里叶变换红外光谱(FTIR)对其表面形貌和化学结构进行了表征。考察了复合薄膜的损耗因子(tan δ)、介电常数、介电常数、电导率和虚介电常数等电学特性。在室温下,测量的频率范围从300赫兹到8兆赫。ε^ ';聚合物/还原氧化石墨烯的介电常数和虚介电常数(ε^ ")随频率的增加而迅速减小。复合材料的交流电导率也同样随着频率的增加而增加。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Progress on Polyolefin/Graphene Nanocomposites with high dielectric constant and low dielectric loss for electrical applications
The attached oxygen functional group in graphene oxide (GO) with layers that are about 1.1 ± 0.2 nm thick, has hindered the performance of electrical characteristics. Diminution of the oxygen functional group, and increasing the carbon/oxygen (C/O) ratio can enhance electrical conductivity. This study investigated the effect of graphene derivatives (C/O) ratios on the dielectric properties of low-density polyethylene (PE) made of metallocene, as well as polypropylene (PP) and mixtures of them. The oxygen functional groups were reduced by utilizing graphene oxide (GO) and reduced graphene oxide (rGO). The effect of GO and rGO-based polyolefin produced by solution blending while lowering the oxygen functional group is explored. The surface morphology and chemical structure were examined by using a scanning electron microscope (SEM) and Fourier Transformed Infrared Spectroscopy (FTIR). The electrical characteristics of the composite films, such as their loss factor (tan δ) and dielectric constant, permittivity and conductivity, and imaginary permittivity were examined. At room temperature, measurements were performed at frequencies ranging from 300 Hz to 8 MHz. ε^'; the dielectric permittivity and imaginary permittivity (ε^'') of polymer/ reduced graphene oxidehowever, these values rapidly decreased with increasing frequency. The alternating current conductivity of the composites was likewise shown to increase with increasing frequency.
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来源期刊
Current Nanomaterials
Current Nanomaterials Materials Science-Materials Science (miscellaneous)
CiteScore
1.60
自引率
0.00%
发文量
53
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