矩形光栅形金纳米结构中纵向和u形局域表面等离子体模之间的强耦合

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2023-01-01 DOI:10.1117/1.JNP.17.016010

Xiaorui Wang, Shijie Xu

{"title":"矩形光栅形金纳米结构中纵向和u形局域表面等离子体模之间的强耦合","authors":"Xiaorui Wang, Shijie Xu","doi":"10.1117/1.JNP.17.016010","DOIUrl":null,"url":null,"abstract":"Abstract. Strong couplings between localized surface plasmon resonance (LSPR) modes and single quantum emitters have been intensively investigated recently, and meanwhile the coupling between different LSPR modes inside individual metallic nanoparticle is still rarely researched. Herein, the strong coupling is investigated for different LSPR modes inside individual rectangular-grating-shaped gold nanostructure composed of one main-cuboid and two side-attached subcuboids. Original uncoupled LSPR modes are revealed to be longitudinal and U-shaped LSPRs. For the nanostructure with increased main-cuboid length, the dispersion curves of simulated dual-original LSPR scattering wavelengths and dual-coupled LSPR scattering wavelengths show typical strong coupling patterns featuring anti-crossing and large Rabi splitting of 598.1 meV. The strong coupling is considered to be caused by the overlap of longitudinal and U-shaped LSPR oscillation modes in the gold nanostructure. The extracted coupling strength is found in order of 1013 Hz and it increases with the LSPR overlap length. The spatial mode and time evolution of the coupled LSPR modes are also numerically investigated. The simulated results are well comprehended with the classical strong coupling model of oscillators, further confirming the coupling between the longitudinal and the U-shaped LSPRs. The experimental dark-field scattering spectrum shows the existence of U-shaped LSPR mode in the gold nanostructure.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Strong coupling between longitudinal and U-shaped localized surface plasmon modes in rectangular grating-shaped gold nanostructures\",\"authors\":\"Xiaorui Wang, Shijie Xu\",\"doi\":\"10.1117/1.JNP.17.016010\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract. Strong couplings between localized surface plasmon resonance (LSPR) modes and single quantum emitters have been intensively investigated recently, and meanwhile the coupling between different LSPR modes inside individual metallic nanoparticle is still rarely researched. Herein, the strong coupling is investigated for different LSPR modes inside individual rectangular-grating-shaped gold nanostructure composed of one main-cuboid and two side-attached subcuboids. Original uncoupled LSPR modes are revealed to be longitudinal and U-shaped LSPRs. For the nanostructure with increased main-cuboid length, the dispersion curves of simulated dual-original LSPR scattering wavelengths and dual-coupled LSPR scattering wavelengths show typical strong coupling patterns featuring anti-crossing and large Rabi splitting of 598.1 meV. The strong coupling is considered to be caused by the overlap of longitudinal and U-shaped LSPR oscillation modes in the gold nanostructure. The extracted coupling strength is found in order of 1013 Hz and it increases with the LSPR overlap length. The spatial mode and time evolution of the coupled LSPR modes are also numerically investigated. The simulated results are well comprehended with the classical strong coupling model of oscillators, further confirming the coupling between the longitudinal and the U-shaped LSPRs. The experimental dark-field scattering spectrum shows the existence of U-shaped LSPR mode in the gold nanostructure.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1117/1.JNP.17.016010\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1117/1.JNP.17.016010","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

摘要局域表面等离子体共振（LSPR）模式与单个量子发射器之间的强耦合最近得到了深入研究，而单个金属纳米颗粒内部不同LSPR模式之间的耦合仍然很少研究。本文研究了由一个主长方体和两个侧面附着的亚长方体组成的单个矩形光栅形金纳米结构内不同LSPR模式的强耦合。原始的非耦合LSPR模式被揭示为纵向和U形LSPR。对于主长方体长度增加的纳米结构，模拟的双原始LSPR散射波长和双耦合LSPR散射波长处的色散曲线显示出典型的强耦合模式，具有抗交叉和598.1meV的大拉比分裂。强耦合被认为是由金纳米结构中纵向和U形LSPR振荡模式的重叠引起的。提取的耦合强度为1013 Hz，并且它随着LSPR重叠长度而增加。数值研究了耦合LSPR模式的空间模式和时间演化。模拟结果与振荡器的经典强耦合模型相吻合，进一步证实了纵向和U形LSPR之间的耦合。实验暗场散射光谱表明金纳米结构中存在U型LSPR模式。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Strong coupling between longitudinal and U-shaped localized surface plasmon modes in rectangular grating-shaped gold nanostructures

Abstract. Strong couplings between localized surface plasmon resonance (LSPR) modes and single quantum emitters have been intensively investigated recently, and meanwhile the coupling between different LSPR modes inside individual metallic nanoparticle is still rarely researched. Herein, the strong coupling is investigated for different LSPR modes inside individual rectangular-grating-shaped gold nanostructure composed of one main-cuboid and two side-attached subcuboids. Original uncoupled LSPR modes are revealed to be longitudinal and U-shaped LSPRs. For the nanostructure with increased main-cuboid length, the dispersion curves of simulated dual-original LSPR scattering wavelengths and dual-coupled LSPR scattering wavelengths show typical strong coupling patterns featuring anti-crossing and large Rabi splitting of 598.1 meV. The strong coupling is considered to be caused by the overlap of longitudinal and U-shaped LSPR oscillation modes in the gold nanostructure. The extracted coupling strength is found in order of 1013 Hz and it increases with the LSPR overlap length. The spatial mode and time evolution of the coupled LSPR modes are also numerically investigated. The simulated results are well comprehended with the classical strong coupling model of oscillators, further confirming the coupling between the longitudinal and the U-shaped LSPRs. The experimental dark-field scattering spectrum shows the existence of U-shaped LSPR mode in the gold nanostructure.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.