M. Handa, H. Kamada, D. Yoshioka, I. Hiromitsu, K. Kasuga, M. Mikuriya
{"title":"由三氟乙酸钼(II)和铜(II)席夫碱组分构建的超分子配合物的晶体结构[{CuLt-Bu}2{Mo2(O2CCF3)4}3(H2O)2]n,H2Lt-Bu=2,3-双((5-叔丁基-2-羟基亚苄基)氨基)-2,3-丁二腈","authors":"M. Handa, H. Kamada, D. Yoshioka, I. Hiromitsu, K. Kasuga, M. Mikuriya","doi":"10.2116/XRAYSTRUCT.34.59","DOIUrl":null,"url":null,"abstract":"There has been much interest for the use of tetracarboxylato dimetal complexes with a lantern-like structure as building blocks in combination with bridging ligands to construct two or three-dimensional architectures, because they show remarkable properties, such as gas-occlusion and ferrior ferromagnetism.1–3 Here, we report on a new assembled complex, [{CuL}2 {Mo2(O2CCF3)4}3(H2O)2] (1), H2L = 2,3-bis((5-tert-butyl-2hydroxybenzylidene)amino)-2,3-butenedinitrile. The copper(II) complex with a Schiff-base ligand ([CuLt-Bu]) is paramagnetic, based on the d9 configuration, although the lantern-type dinuclear molybdenum(II) complex is diamagnetic based on the σ2π4δ2 configuration of the Mo–Mo quadruple bond core. The phenoxido oxygen of [CuLt-Bu] was shown to participate in the axial interaction with the molybdenum(II) dinuclear core to assemble the component complex units, giving the supramolecular chain structure (Fig. 1).","PeriodicalId":23922,"journal":{"name":"X-ray Structure Analysis Online","volume":null,"pages":null},"PeriodicalIF":0.1000,"publicationDate":"2018-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal Structure of a Supramolecular Complex Built up from Molybdenum(II) Trifluoroacetate and Copper(II) Schiff-Base Components, [{CuLt-Bu}2{Mo2(O2CCF3)4}3(H2O)2]n, H2Lt-Bu = 2,3-bis((5-tert-butyl-2-hydroxybenzylidene)amino)-2,3-butenedinitrile\",\"authors\":\"M. Handa, H. Kamada, D. Yoshioka, I. Hiromitsu, K. Kasuga, M. Mikuriya\",\"doi\":\"10.2116/XRAYSTRUCT.34.59\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"There has been much interest for the use of tetracarboxylato dimetal complexes with a lantern-like structure as building blocks in combination with bridging ligands to construct two or three-dimensional architectures, because they show remarkable properties, such as gas-occlusion and ferrior ferromagnetism.1–3 Here, we report on a new assembled complex, [{CuL}2 {Mo2(O2CCF3)4}3(H2O)2] (1), H2L = 2,3-bis((5-tert-butyl-2hydroxybenzylidene)amino)-2,3-butenedinitrile. The copper(II) complex with a Schiff-base ligand ([CuLt-Bu]) is paramagnetic, based on the d9 configuration, although the lantern-type dinuclear molybdenum(II) complex is diamagnetic based on the σ2π4δ2 configuration of the Mo–Mo quadruple bond core. The phenoxido oxygen of [CuLt-Bu] was shown to participate in the axial interaction with the molybdenum(II) dinuclear core to assemble the component complex units, giving the supramolecular chain structure (Fig. 1).\",\"PeriodicalId\":23922,\"journal\":{\"name\":\"X-ray Structure Analysis Online\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.1000,\"publicationDate\":\"2018-12-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/XRAYSTRUCT.34.59\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/XRAYSTRUCT.34.59","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
Crystal Structure of a Supramolecular Complex Built up from Molybdenum(II) Trifluoroacetate and Copper(II) Schiff-Base Components, [{CuLt-Bu}2{Mo2(O2CCF3)4}3(H2O)2]n, H2Lt-Bu = 2,3-bis((5-tert-butyl-2-hydroxybenzylidene)amino)-2,3-butenedinitrile
There has been much interest for the use of tetracarboxylato dimetal complexes with a lantern-like structure as building blocks in combination with bridging ligands to construct two or three-dimensional architectures, because they show remarkable properties, such as gas-occlusion and ferrior ferromagnetism.1–3 Here, we report on a new assembled complex, [{CuL}2 {Mo2(O2CCF3)4}3(H2O)2] (1), H2L = 2,3-bis((5-tert-butyl-2hydroxybenzylidene)amino)-2,3-butenedinitrile. The copper(II) complex with a Schiff-base ligand ([CuLt-Bu]) is paramagnetic, based on the d9 configuration, although the lantern-type dinuclear molybdenum(II) complex is diamagnetic based on the σ2π4δ2 configuration of the Mo–Mo quadruple bond core. The phenoxido oxygen of [CuLt-Bu] was shown to participate in the axial interaction with the molybdenum(II) dinuclear core to assemble the component complex units, giving the supramolecular chain structure (Fig. 1).