SPVD法制备纳米结构过渡金属氧化物

IF 1.9 Q3 ENGINEERING, MANUFACTURING

Manufacturing Review Pub Date : 2020-02-01 DOI:10.1051/mfreview/2020009

A. Plăiașu, M. C. Ducu, S. Moga, A. Negrea, E. M. Modan

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引用次数: 2

摘要

近十年来，人们对具有纳米级结构的材料的独特性能的兴趣呈指数级增长。过渡金属氧化物是催化应用的首选材料，因为它们的半填充d轨道使它们以不同的氧化态存在。过渡金属氧化物表现出广泛的结构变化，因为它们能够形成不同金属氧比的相，反映金属离子的多种稳定氧化状态。本文提出的太阳能物理气相沉积法(SPVD)是一种在2kw太阳能电炉中集中太阳光下制备纳米粉体的新方法。采用XRD、SEM和EDX等手段系统研究了合成参数对锌锰氧化物纳米相化学和微观结构的影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Nanostructured transition metal oxides obtained by SPVD

The interest in the unique properties associated with materials having structures on a nanometer scale has been increasing at an exponential rate in last decade. Transition metal oxides are preferred materials for catalytic applications due to their half-filled d orbitals that make them exist in different oxidation states. Transition metal oxides show a broad structural variety due to their ability to form phases of varying metal to oxygen ratios reflecting multiple stable oxidation states of the metal ions. The Solar Physical Vapor Deposition (SPVD) presented in the paper as elaboration method is an original process to prepare nanopowders working under concentrated sunlight in 2 kW solar furnaces. The influence of the synthesis parameters on the chemical and microstructural characteristics of zinc and manganese oxides synthesized nanophases has been systematically studied using XRD, SEM and EDX.

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来源期刊

Manufacturing Review ENGINEERING, MANUFACTURING-

CiteScore

5.40

自引率

12.00%

发文量

审稿时长

8 weeks

期刊介绍： The aim of the journal is to stimulate and record an international forum for disseminating knowledge on the advances, developments and applications of manufacturing engineering, technology and applied sciences with a focus on critical reviews of developments in manufacturing and emerging trends in this field. The journal intends to establish a specific focus on reviews of developments of key core topics and on the emerging technologies concerning manufacturing engineering, technology and applied sciences, the aim of which is to provide readers with rapid and easy access to definitive and authoritative knowledge and research-backed opinions on future developments. The scope includes, but is not limited to critical reviews and outstanding original research papers on the advances, developments and applications of: Materials for advanced manufacturing (Metals, Polymers, Glass, Ceramics, Composites, Nano-materials, etc.) and recycling, Material processing methods and technology (Machining, Forming/Shaping, Casting, Powder Metallurgy, Laser technology, Joining, etc.), Additive/rapid manufacturing methods and technology, Tooling and surface-engineering technology (fabrication, coating, heat treatment, etc.), Micro-manufacturing methods and technology, Nano-manufacturing methods and technology, Advanced metrology, instrumentation, quality assurance, testing and inspection, Mechatronics for manufacturing automation, Manufacturing machinery and manufacturing systems, Process chain integration and manufacturing platforms, Sustainable manufacturing and Life-cycle analysis, Industry case studies involving applications of the state-of-the-art manufacturing methods, technology and systems. Content will include invited reviews, original research articles, and invited special topic contributions.