{"title":"球磨和HF浸出膨胀石墨的结构和形态表征","authors":"S. Karimi, A. Heidarpour, S. Ghasemi","doi":"10.22068/IJMSE.2131","DOIUrl":null,"url":null,"abstract":"In this research, expanded graphite (EG) was successfully fabricated using a simple ball milling process followed by hydrofluoric (HF, 10 wt. %) leaching. The effect of ball milling time (0-15 h) and leaching time (1-24 h) on the exfoliation of graphite were examined by XRD and Raman spectroscopy. Furthermore, the morphological evaluation of the obtained expanded graphite samples was carried out by scanning electron microscopy (SEM). The XRD results of the ball-milled and HF treated samples showed a slight peak shift and broadening of (002) plane for expanded graphitein in comparison to the precursor and HF-treated samples. Moreover, the intensity of the (002) planes remarkably decreased by the ball milling process but remained constant after HF treatment. Raman spectra of the samples confirmed the ordering process only in HF-treated specimens. Moreover, the intensity ratio of 2D1 to 2D2 band gradually increased with enhancing the HF treatment time up to 5 hrs, indicating a decrement in the number of graphite layers by leaching in the HF solution","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2021-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structural and Morphological Characterization of the Expanded Graphite Obtained by Ball Milling and HF Leaching\",\"authors\":\"S. Karimi, A. Heidarpour, S. Ghasemi\",\"doi\":\"10.22068/IJMSE.2131\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this research, expanded graphite (EG) was successfully fabricated using a simple ball milling process followed by hydrofluoric (HF, 10 wt. %) leaching. The effect of ball milling time (0-15 h) and leaching time (1-24 h) on the exfoliation of graphite were examined by XRD and Raman spectroscopy. Furthermore, the morphological evaluation of the obtained expanded graphite samples was carried out by scanning electron microscopy (SEM). The XRD results of the ball-milled and HF treated samples showed a slight peak shift and broadening of (002) plane for expanded graphitein in comparison to the precursor and HF-treated samples. Moreover, the intensity of the (002) planes remarkably decreased by the ball milling process but remained constant after HF treatment. Raman spectra of the samples confirmed the ordering process only in HF-treated specimens. Moreover, the intensity ratio of 2D1 to 2D2 band gradually increased with enhancing the HF treatment time up to 5 hrs, indicating a decrement in the number of graphite layers by leaching in the HF solution\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2021-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22068/IJMSE.2131\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22068/IJMSE.2131","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Structural and Morphological Characterization of the Expanded Graphite Obtained by Ball Milling and HF Leaching
In this research, expanded graphite (EG) was successfully fabricated using a simple ball milling process followed by hydrofluoric (HF, 10 wt. %) leaching. The effect of ball milling time (0-15 h) and leaching time (1-24 h) on the exfoliation of graphite were examined by XRD and Raman spectroscopy. Furthermore, the morphological evaluation of the obtained expanded graphite samples was carried out by scanning electron microscopy (SEM). The XRD results of the ball-milled and HF treated samples showed a slight peak shift and broadening of (002) plane for expanded graphitein in comparison to the precursor and HF-treated samples. Moreover, the intensity of the (002) planes remarkably decreased by the ball milling process but remained constant after HF treatment. Raman spectra of the samples confirmed the ordering process only in HF-treated specimens. Moreover, the intensity ratio of 2D1 to 2D2 band gradually increased with enhancing the HF treatment time up to 5 hrs, indicating a decrement in the number of graphite layers by leaching in the HF solution
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.