CdTe中取代氧天然同位素的局域振动模式

IF 1.4 Q3 PHYSICS, MULTIDISCIPLINARY
E. Tarhan, A. Ramdas
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引用次数: 3

摘要

我们在低温下使用红外吸收光谱研究了碲化镉中取代碲位处含有$^{16}$O、$^{17}$O和$^{18}$O同位素的天然氧的局域振动模式LVM。在350cm$^{-1\,}$处观察到的主吸收峰以前归因于碲位置处氧的基本LVM模式$\nu_{0}$。根据它们的相对强度和光谱位置,在331 cm$^{-1\,}$和340 cm$^{-1\,}$处观察到的相对较弱的吸收峰分别被指定为$^{17}$O和$^{18}$O同位素的相同$nu_{0}$模式。光谱位置通过使用线性链模型的理论计算得到确认,其中350厘米$^{-1}$处的峰值位置被用作$^{16}$O同位素的参考。通过对观测到的峰值位置进行最小二乘分析,我们能够根据微扰理论计算出力常数。考虑到同位素质量和宿主Cd原子自然丰度变化的影响,还对每个$\nu_{0}$吸收峰进行了洛伦兹线形分析,以进一步确认它们的归属。对于所有氧同位素的$\nu_{0}$模,获得了相当好的线形拟合。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Local vibrational modes of natural isotopes of substitutional oxygen in CdTe
We investigated the localized vibrational modes LVM of natural oxygen containing $^{16}$O, $^{17}$O, and $^{18}$O isotopes at a substitutional tellurium site in cadmium telluride using infrared absorption spectroscopy at cryogenic temperatures. The main absorption peak observed at 350 cm$^{-1\, }$was formerly attributed to a fundamental LVM mode $\nu _{0} $ of oxygen at a tellurium site. The relatively weak absorption peaks observed at 331 cm$^{-1\, }$and 340 cm$^{-1\, }$are assigned as the same $\nu_{0}$ mode of the $^{17}$O and $^{18}$O isotopes, respectively, based on their relative intensities and spectral positions. The spectral positions were confirmed with theoretical calculations using a linear chain model where the peak position at 350 cm$^{-1}$ was taken as the reference for the $^{16}$O isotope. From a least square analysis of the observed peak positions we were able to calculate the force constants from perturbation theory. A Lorentzian line shape analysis of each $\nu_{0}$ absorption peak, considering the effects of isotopic mass and natural abundance variations of the host Cd atoms, was also carried out to further confirm their assignments. Reasonably good line shape fittings were obtained for $\nu _{0}$ modes of all isotopes of oxygen.
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来源期刊
Turkish Journal of Physics
Turkish Journal of Physics PHYSICS, MULTIDISCIPLINARY-
CiteScore
3.50
自引率
0.00%
发文量
8
期刊介绍: The Turkish Journal of Physics is published electronically 6 times a year by the Scientific and Technological Research Council of Turkey (TÜBİTAK) and accepts English-language manuscripts in various fields of research in physics, astrophysics, and interdisciplinary topics related to physics. Contribution is open to researchers of all nationalities.
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