内嵌金属富勒烯功能化研究进展

IF 3.1 4区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Inorganics Pub Date : 2023-08-21 DOI:10.3390/inorganics11080346

Song Wang, Xianming Zhang, Xi Tan, Hongzhen Li, Songxin Dai, B. Yao, Xingyan Liu, Youzhou He, Fei Jin

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引用次数: 0

摘要

内嵌金属富勒烯（EMFs）的功能化在探索EMFs的反应性和稳定缺失的EMFs方面发挥着重要作用，从而赋予EMFs可调的性质，并将其转化为适用的材料。在这篇综述中，我们介绍了自2019年以来在EMF功能化方面的详尽进展。综述了经典的官能化反应，包括Prato反应、Bingel–Hirsch反应、自由基加成反应、卡宾加成反应等。并提出了新的复杂多组分反应和其他创造性反应。我们还讨论了EMFs衍生物的结构特征和相应的反应机制，以了解EMFs的反应性和区域选择性。最后，我们得出结论，并对EMFs的功能化前景提出展望。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Recent Progress on the Functionalization of Endohedral Metallofullerenes

Functionalization of endohedral metallofullerenes (EMFs) plays an important role in exploring the reactivity of EMFs and stabilizing missing EMFs, thus conferring tunable properties and turning EMFs into applicable materials. In this review, we present exhaustive progress on the functionalization of EMFs since 2019. Classic functionalization reactions include Prato reactions, Bingel–Hirsch reactions, radical addition reactions, carbene addition reactions, and so on are summarized. And new complicated multi-component reactions and other creative reactions are presented as well. We also discuss the structural features of derivatives of EMFs and the corresponding reaction mechanisms to understand the reactivity and regioselectivity of EMFs. In the end, we make conclusions and put forward an outlook on the prospect of the functionalization of EMFs.

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来源期刊

Inorganics Chemistry-Inorganic Chemistry

CiteScore

2.80

自引率

10.30%

发文量

193

审稿时长

6 weeks

期刊介绍： Inorganics is an open access journal that covers all aspects of inorganic chemistry research. Topics include but are not limited to: synthesis and characterization of inorganic compounds, complexes and materials structure and bonding in inorganic molecular and solid state compounds spectroscopic, magnetic, physical and chemical properties of inorganic compounds chemical reactivity, physical properties and applications of inorganic compounds and materials mechanisms of inorganic reactions organometallic compounds inorganic cluster chemistry heterogenous and homogeneous catalytic reactions promoted by inorganic compounds thermodynamics and kinetics of significant new and known inorganic compounds supramolecular systems and coordination polymers bio-inorganic chemistry and applications of inorganic compounds in biological systems and medicine environmental and sustainable energy applications of inorganic compounds and materials MD