聚氨酯粘结剂NCO/OH当量比和粘结剂用量对中密度纤维板性能的影响

IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences
Mohd Norhisham Sattar
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引用次数: 0

摘要

将生物基粘合剂用于中密度纤维板(MDF)的潜力越来越受到关注。然而,尚未对棕榈基聚氨酯(PU)作为MDF生物基粘合剂的潜力进行研究。因此,研究了棕榈油基PU粘合剂中异氰酸酯(NCO)和羟基(OH)的当量比以及粘合剂含量对MDF性能的影响。以1.5/1(PU1.5)、2.0/1(PU2.0)和2.5/1(PU2.5)的NCO和OH的不同当量比制备棕榈油基PU粘合剂,并且在MDF的制备中使用3%、5%、7%和10%的粘合剂含量。使用傅立叶变换红外光谱和热重分析对多元醇、NCO和棕榈油基PU粘合剂进行了表征。随着NCO和OH的当量比以及粘结剂含量的增加,MDF的断裂模量、弹性模量和内部粘结不断增加。厚度膨胀和水分含量随着NCO和OH的当量比以及粘合剂含量的增加而降低。通常,用PU2.0制备的粘合剂含量为7%的MDF符合所有英国标准(BS EN 622-52009)的要求,表明其适用于MDF应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
THE EFFECT OF NCO/OH EQUIVALENT WEIGHT RATIOS OF POLYURETHANE (PU) BINDER AND PU BINDER CONTENT ON PROPERTIES OF MEDIUM DENSITY FIBERBOARD (MDF)
The potential of using bio-based binders for medium density fiberboard (MDF) has received increased attention. However, no study was done on the potential of palm-based polyurethane (PU) as biobased binder in MDF. Therefore, an investigation on the effect of equivalent weight ratios of isocyanate (NCO) and hydroxyl group (OH) of palm oil-based PU binder and binder content on the properties of MDF was conducted. Palm oil-based PU binders were prepared at different equivalent weight ratios of NCO and OH at 1.5/1 (PU1.5), 2.0/1 (PU2.0) and 2.5/1 (PU2.5) and binder content at 3%, 5%, 7% and 10% were used in the preparation of MDF. The polyol, NCO and palm oil-based PU binders were characterised using Fourier transform infrared spectroscopy and thermogravimetric analysis. As equivalent weight ratios of NCO and OH and binder content increased, the modulus of rupture, modulus of elasticity and internal bonding of MDF were consistently increased. Thickness swelling and moisture content decreased with increased equivalent weight ratios of NCO and OH and binder content. In general, MDF prepared with PU2.0 with 7% binder content fulfills all British Standard (BS EN 622-5, 2009) requirements, indicating its suitability for MDF application.
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来源期刊
Journal of Oil Palm Research
Journal of Oil Palm Research 农林科学-食品科技
CiteScore
2.60
自引率
30.80%
发文量
69
审稿时长
>12 weeks
期刊介绍: JOURNAL OF OIL PALM RESEARCH, an international refereed journal, carries full-length original research papers and scientific review papers on various aspects of oil palm and palm oil and other palms. It also publishes short communications, letters to editor and reviews of relevant books. JOURNAL OF OIL PALM RESEARCH is published four times per year, i.e. March, June, September and December.
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