Puning Ren, Yue Zhou, Kaiyi Su, Lulu Sun, Dr. Nengchao Luo, Prof. Feng Wang
{"title":"可见光下CuOx/Nb2O5光催化氧化糠醛。","authors":"Puning Ren, Yue Zhou, Kaiyi Su, Lulu Sun, Dr. Nengchao Luo, Prof. Feng Wang","doi":"10.1002/asia.202300732","DOIUrl":null,"url":null,"abstract":"<p>Maleic anhydride (MA) is an important polyester monomer that can be produced from oxidizing renewable furfural derived from biomass. However, MA generation from furfural requires harsh reaction conditions, and suffers from low efficiency and solvent corrosion. Herein, we design a Nb<sub>2</sub>O<sub>5</sub> photocatalyst loaded of highly dispersed CuO<sub>x</sub> (CuO<sub>x</sub>/Nb<sub>2</sub>O<sub>5</sub>), which selectively catalyzes furfural oxidation to MA and the precursor (5-hydroxy-2(5<i>H</i>)-furanone, HF). Due to CuO<sub>x</sub> loading and forming a complex of ligand to metal charge transfer (LMCT) between the Nb<sub>2</sub>O<sub>5</sub> surface and adsorbed furfural, the CuO<sub>x</sub>/Nb<sub>2</sub>O<sub>5</sub> absorbs visible light to activate furfural though Nb<sub>2</sub>O<sub>5</sub> has a large band-gap energy (3.2 eV). Singlet oxygen (<sup>1</sup>O<sub>2</sub>) is the key active species for C−C bond cleavage and CO generation. MA and HF is produced with a combined yield of 59 % under optimized conditions. This work provides a mild way to provide renewable maleic anhydride via oxidative C−C bond cleavage.</p>","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":"18 22","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2023-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Visible-Light-Driven Furfural Oxidation over CuOx/Nb2O5\",\"authors\":\"Puning Ren, Yue Zhou, Kaiyi Su, Lulu Sun, Dr. Nengchao Luo, Prof. Feng Wang\",\"doi\":\"10.1002/asia.202300732\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Maleic anhydride (MA) is an important polyester monomer that can be produced from oxidizing renewable furfural derived from biomass. However, MA generation from furfural requires harsh reaction conditions, and suffers from low efficiency and solvent corrosion. Herein, we design a Nb<sub>2</sub>O<sub>5</sub> photocatalyst loaded of highly dispersed CuO<sub>x</sub> (CuO<sub>x</sub>/Nb<sub>2</sub>O<sub>5</sub>), which selectively catalyzes furfural oxidation to MA and the precursor (5-hydroxy-2(5<i>H</i>)-furanone, HF). Due to CuO<sub>x</sub> loading and forming a complex of ligand to metal charge transfer (LMCT) between the Nb<sub>2</sub>O<sub>5</sub> surface and adsorbed furfural, the CuO<sub>x</sub>/Nb<sub>2</sub>O<sub>5</sub> absorbs visible light to activate furfural though Nb<sub>2</sub>O<sub>5</sub> has a large band-gap energy (3.2 eV). Singlet oxygen (<sup>1</sup>O<sub>2</sub>) is the key active species for C−C bond cleavage and CO generation. MA and HF is produced with a combined yield of 59 % under optimized conditions. This work provides a mild way to provide renewable maleic anhydride via oxidative C−C bond cleavage.</p>\",\"PeriodicalId\":145,\"journal\":{\"name\":\"Chemistry - An Asian Journal\",\"volume\":\"18 22\",\"pages\":\"\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2023-09-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry - An Asian Journal\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/asia.202300732\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - An Asian Journal","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/asia.202300732","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Visible-Light-Driven Furfural Oxidation over CuOx/Nb2O5
Maleic anhydride (MA) is an important polyester monomer that can be produced from oxidizing renewable furfural derived from biomass. However, MA generation from furfural requires harsh reaction conditions, and suffers from low efficiency and solvent corrosion. Herein, we design a Nb2O5 photocatalyst loaded of highly dispersed CuOx (CuOx/Nb2O5), which selectively catalyzes furfural oxidation to MA and the precursor (5-hydroxy-2(5H)-furanone, HF). Due to CuOx loading and forming a complex of ligand to metal charge transfer (LMCT) between the Nb2O5 surface and adsorbed furfural, the CuOx/Nb2O5 absorbs visible light to activate furfural though Nb2O5 has a large band-gap energy (3.2 eV). Singlet oxygen (1O2) is the key active species for C−C bond cleavage and CO generation. MA and HF is produced with a combined yield of 59 % under optimized conditions. This work provides a mild way to provide renewable maleic anhydride via oxidative C−C bond cleavage.
期刊介绍：
Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics.
Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews.
A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal.
Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
