Evgeniya V Timakova, Liubov I Afonina, Tatiana N Drebushchak, Boris A Zakharov
{"title":"两种新的琥珀酸铋盐：合成、结构、光谱和热表征。","authors":"Evgeniya V Timakova, Liubov I Afonina, Tatiana N Drebushchak, Boris A Zakharov","doi":"10.1107/S2053229623008124","DOIUrl":null,"url":null,"abstract":"<p><p>Two novel bismuth succinate hydrates, namely, poly[[diaqua(μ<sub>3</sub>-butane-1,4-dicarboxylato)hemi(μ-butane-1,4-dicarboxylato)bismuth] monohydrate], {[Bi(C<sub>4</sub>H<sub>4</sub>O<sub>4</sub>)<sub>1.5</sub>(H<sub>2</sub>O)<sub>2</sub>]·H<sub>2</sub>O}<sub>n</sub> (1), and poly[[μ-aqua-aqua(μ<sub>3</sub>-butane-1,4-dicarboxylato)(μ-butane-1,4-dicarboxylato)-μ-oxido-dibismuth] monohydrate], {[Bi<sub>2</sub>(C<sub>4</sub>H<sub>4</sub>O<sub>4</sub>)<sub>2</sub>O(H<sub>2</sub>O)<sub>2</sub>]·H<sub>2</sub>O}<sub>n</sub> (2), have been synthesized. Their crystal structures were determined by single-crystal X-ray diffraction and the compounds were characterized by IR and Raman spectroscopy, powder X-ray diffraction and thermal analysis. The crystal structure analysis revealed that the compounds are coordination polymers, with 1 having a two-dimensional layered structure and 2 displaying a three-dimensional (3D) framework. Fully deprotonated succinate anions (C<sub>4</sub>H<sub>4</sub>O<sub>4</sub><sup>2-</sup>) in two different conformations (trans and gauche) are included in their composition. The Bi<sup>3+</sup> cations are surrounded by O atoms from the carboxylate groups of succinate anions and aqua ligands. BiO<sub>9</sub> coordination polyhedra in 1 are connected in pairs by edges. These pairs are bound together by bridging succinate ligands to form layers. Bismuth coordination polyhedra of two different types (BiO<sub>9</sub> and BiO<sub>7</sub>) in 2 are connected by edges to form infinite ribbons. Ribbons of polyhedra with bridging succinate ligands form a 3D polymeric structure.</p>","PeriodicalId":7115,"journal":{"name":"Acta Crystallographica Section C Structural Chemistry","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Two new bismuth salts with succinic acid: synthesis, structural, spectroscopic and thermal characterization.\",\"authors\":\"Evgeniya V Timakova, Liubov I Afonina, Tatiana N Drebushchak, Boris A Zakharov\",\"doi\":\"10.1107/S2053229623008124\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Two novel bismuth succinate hydrates, namely, poly[[diaqua(μ<sub>3</sub>-butane-1,4-dicarboxylato)hemi(μ-butane-1,4-dicarboxylato)bismuth] monohydrate], {[Bi(C<sub>4</sub>H<sub>4</sub>O<sub>4</sub>)<sub>1.5</sub>(H<sub>2</sub>O)<sub>2</sub>]·H<sub>2</sub>O}<sub>n</sub> (1), and poly[[μ-aqua-aqua(μ<sub>3</sub>-butane-1,4-dicarboxylato)(μ-butane-1,4-dicarboxylato)-μ-oxido-dibismuth] monohydrate], {[Bi<sub>2</sub>(C<sub>4</sub>H<sub>4</sub>O<sub>4</sub>)<sub>2</sub>O(H<sub>2</sub>O)<sub>2</sub>]·H<sub>2</sub>O}<sub>n</sub> (2), have been synthesized. Their crystal structures were determined by single-crystal X-ray diffraction and the compounds were characterized by IR and Raman spectroscopy, powder X-ray diffraction and thermal analysis. The crystal structure analysis revealed that the compounds are coordination polymers, with 1 having a two-dimensional layered structure and 2 displaying a three-dimensional (3D) framework. Fully deprotonated succinate anions (C<sub>4</sub>H<sub>4</sub>O<sub>4</sub><sup>2-</sup>) in two different conformations (trans and gauche) are included in their composition. The Bi<sup>3+</sup> cations are surrounded by O atoms from the carboxylate groups of succinate anions and aqua ligands. BiO<sub>9</sub> coordination polyhedra in 1 are connected in pairs by edges. These pairs are bound together by bridging succinate ligands to form layers. Bismuth coordination polyhedra of two different types (BiO<sub>9</sub> and BiO<sub>7</sub>) in 2 are connected by edges to form infinite ribbons. Ribbons of polyhedra with bridging succinate ligands form a 3D polymeric structure.</p>\",\"PeriodicalId\":7115,\"journal\":{\"name\":\"Acta Crystallographica Section C Structural Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Crystallographica Section C Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1107/S2053229623008124\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2023/9/21 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Crystallographica Section C Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1107/S2053229623008124","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2023/9/21 0:00:00","PubModel":"Epub","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Two new bismuth salts with succinic acid: synthesis, structural, spectroscopic and thermal characterization.
Two novel bismuth succinate hydrates, namely, poly[[diaqua(μ3-butane-1,4-dicarboxylato)hemi(μ-butane-1,4-dicarboxylato)bismuth] monohydrate], {[Bi(C4H4O4)1.5(H2O)2]·H2O}n (1), and poly[[μ-aqua-aqua(μ3-butane-1,4-dicarboxylato)(μ-butane-1,4-dicarboxylato)-μ-oxido-dibismuth] monohydrate], {[Bi2(C4H4O4)2O(H2O)2]·H2O}n (2), have been synthesized. Their crystal structures were determined by single-crystal X-ray diffraction and the compounds were characterized by IR and Raman spectroscopy, powder X-ray diffraction and thermal analysis. The crystal structure analysis revealed that the compounds are coordination polymers, with 1 having a two-dimensional layered structure and 2 displaying a three-dimensional (3D) framework. Fully deprotonated succinate anions (C4H4O42-) in two different conformations (trans and gauche) are included in their composition. The Bi3+ cations are surrounded by O atoms from the carboxylate groups of succinate anions and aqua ligands. BiO9 coordination polyhedra in 1 are connected in pairs by edges. These pairs are bound together by bridging succinate ligands to form layers. Bismuth coordination polyhedra of two different types (BiO9 and BiO7) in 2 are connected by edges to form infinite ribbons. Ribbons of polyhedra with bridging succinate ligands form a 3D polymeric structure.
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Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.
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