{"title":"二次pH测量法在标准物质均匀性和稳定性评价中的应用","authors":"Boryana Koleva, Lyudmila Dimitrova, Daniela Stoica, Paola Fisicaro","doi":"10.1007/s00769-021-01464-w","DOIUrl":null,"url":null,"abstract":"<p>In this work, the development and optimization of a secondary method for pH measurement using a differential potentiometric cell are described. The method was optimized and validated by measurement of three certified primary buffer solutions (CRMs) with nominal pH values of 4.005, 6.865 and 9.180 at 25?°C. The method was applied to assess homogeneity and stability of phosphate buffer solution with nominal pH of 7.000 at 25?°C which will be used as test item in proficiency testing schemes for pH measurement of testing laboratories. The experiments carried out and described in this article proved that this particular design of secondary differential potentiometric cell requires small volume of solutions, is fast, accurate and precise and is suitable for the characterization of secondary buffer solutions and assessment of homogeneity and stability of buffer solutions.</p>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":"26 2","pages":"113 - 120"},"PeriodicalIF":0.8000,"publicationDate":"2021-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s00769-021-01464-w","citationCount":"3","resultStr":"{\"title\":\"Application of secondary pH measurement method for homogeneity and stability assessment of reference materials\",\"authors\":\"Boryana Koleva, Lyudmila Dimitrova, Daniela Stoica, Paola Fisicaro\",\"doi\":\"10.1007/s00769-021-01464-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this work, the development and optimization of a secondary method for pH measurement using a differential potentiometric cell are described. The method was optimized and validated by measurement of three certified primary buffer solutions (CRMs) with nominal pH values of 4.005, 6.865 and 9.180 at 25?°C. The method was applied to assess homogeneity and stability of phosphate buffer solution with nominal pH of 7.000 at 25?°C which will be used as test item in proficiency testing schemes for pH measurement of testing laboratories. The experiments carried out and described in this article proved that this particular design of secondary differential potentiometric cell requires small volume of solutions, is fast, accurate and precise and is suitable for the characterization of secondary buffer solutions and assessment of homogeneity and stability of buffer solutions.</p>\",\"PeriodicalId\":454,\"journal\":{\"name\":\"Accreditation and Quality Assurance\",\"volume\":\"26 2\",\"pages\":\"113 - 120\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2021-04-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1007/s00769-021-01464-w\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accreditation and Quality Assurance\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00769-021-01464-w\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accreditation and Quality Assurance","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s00769-021-01464-w","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Application of secondary pH measurement method for homogeneity and stability assessment of reference materials
In this work, the development and optimization of a secondary method for pH measurement using a differential potentiometric cell are described. The method was optimized and validated by measurement of three certified primary buffer solutions (CRMs) with nominal pH values of 4.005, 6.865 and 9.180 at 25?°C. The method was applied to assess homogeneity and stability of phosphate buffer solution with nominal pH of 7.000 at 25?°C which will be used as test item in proficiency testing schemes for pH measurement of testing laboratories. The experiments carried out and described in this article proved that this particular design of secondary differential potentiometric cell requires small volume of solutions, is fast, accurate and precise and is suitable for the characterization of secondary buffer solutions and assessment of homogeneity and stability of buffer solutions.
期刊介绍：
Accreditation and Quality Assurance has established itself as the leading information and discussion forum for all aspects relevant to quality, transparency and reliability of measurement results in chemical and biological sciences. The journal serves the information needs of researchers, practitioners and decision makers dealing with quality assurance and quality management, including the development and application of metrological principles and concepts such as traceability or measurement uncertainty in the following fields: environment, nutrition, consumer protection, geology, metallurgy, pharmacy, forensics, clinical chemistry and laboratory medicine, and microbiology.
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