咪唑化合物:合成、表征及在光学分析中的应用。

IF 4.2 2区 化学 Q1 CHEMISTRY, ANALYTICAL
Junjie Wang, Xin Ding, Zhenni Lan, Guangyan Liu, Shili Hou, Shifeng Hou
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引用次数: 0

摘要

咪唑是一种五元杂环,含有三个碳原子、两个氮原子和两个双键。在两个氮原子中,一个带有氢原子,是吡咯型氮原子,另一个是吡啶型氮原子。因此,咪唑环属于π电子丰富的芳香环,能接受电子群的强吸力。此外,咪唑环的氮原子可与金属离子配位形成金属有机框架。近年来,由于咪唑类化合物具有独特的光学性质,其在光学分析中的应用受到越来越多的关注。因此,本综述总结了咪唑类化合物的合成、表征和应用,重点介绍了咪唑类化合物在光学分析领域的研究进展,包括荧光探针、比色探针、电化学发光传感器、光纤光学传感器、表面等离子体共振等。本文将为开发高灵敏度和高选择性的含咪唑传感器提出方向性建议。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Imidazole Compounds: Synthesis, Characterization and Application in Optical Analysis.

Imidazole is a five-membered heterocyclic ring containing three carbon atoms, two nitrogen atoms, and two double bonds. Among two nitrogen atoms, one of which carries with a hydrogen atom is a pyrrole-type nitrogen atom, another is a pyridine type nitrogen atom. Hence, the imidazole ring belongs to the π electron-rich aromatic ring and can accept strong suction to the electronic group. Moreover, the nitrogen atom of the imidazole ring is coordinated with metal ions to form metal-organic frameworks. In recent years, because of imidazole compounds' unique optical properties, their applications have attracted more and more attention in optical analysis. Thus, this review has summarized the synthesis, characterization, and application with emphasis on the research progress of imidazole compounds in optical analysis, including fluorescence probe, colorimetric probe, electrochemiluminescence sensor, fiber optical sensor, surface plasmon resonance, etc. This paper will suggest the direction for the development of imidazole-containing sensors with high sensitivity and selectivity.

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来源期刊
CiteScore
12.00
自引率
4.00%
发文量
137
审稿时长
6 months
期刊介绍: Critical Reviews in Analytical Chemistry continues to be a dependable resource for both the expert and the student by providing in-depth, scholarly, insightful reviews of important topics within the discipline of analytical chemistry and related measurement sciences. The journal exclusively publishes review articles that illuminate the underlying science, that evaluate the field''s status by putting recent developments into proper perspective and context, and that speculate on possible future developments. A limited number of articles are of a "tutorial" format written by experts for scientists seeking introduction or clarification in a new area. This journal serves as a forum for linking various underlying components in broad and interdisciplinary means, while maintaining balance between applied and fundamental research. Topics we are interested in receiving reviews on are the following: · chemical analysis; · instrumentation; · chemometrics; · analytical biochemistry; · medicinal analysis; · forensics; · environmental sciences; · applied physics; · and material science.
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