光增强BiOBr/PtRu杂化纳米结构的类酶活性。

IF 1.2 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES
Chuang Liu, Yingying Yan, Yuanyang Mao, Weiwei He
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引用次数: 4

摘要

半导体与金属纳米组分的结合是设计高效光催化剂的有效途径。这一策略有望应用于光调控纳米酶的设计。为了证明这一概念,通过模板共还原法将PtRu纳米颗粒沉积在BiOBr纳米片上,制备了BiOBr/PtRu混合纳米结构。通过TEM、XRD和XPS证实了BiOBr/PtRu杂化纳米结构的形成。BiOBr/PtRu杂化纳米结构表现出优异的酶样活性(过氧化物酶、氧化酶、氧化铁酶)和清除DPPH自由基的能力。当光照射(λ > 420 nm)时,发现BiOBr/PtRu杂化纳米结构不仅具有更好的光催化降解能力,而且具有增强的过氧化物酶和氧化酶样活性。由于光催化作用和异质结带来的较高电荷分离和利用效率,提出了一种光增强类酶活性机制。这些结果对设计高效的光纳米酶具有重要的生物和环境应用价值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Photo-enhanced enzyme-like activities of BiOBr/PtRu hybrid nanostructures.

The combination of semiconductor and metal nanocomponents represents an effective way for design of photocatalysts with high efficiency. It is expected that this strategy can be applied to design photo-regulated nanozymes. To prove this concept, BiOBr/PtRu hybrid nanostructures have been fabricated by depositing PtRu nanoparticles on BiOBr nanosheets through a templating co-reduction method. The formation of BiOBr/PtRu hybrid nanostructures was confirmed by TEM, XRD and XPS. BiOBr/PtRu hybrid nanostructures exhibited excellent enzyme-like activities (peroxidase, oxidase, ferroxidase) as well as the ability to scavenge DPPH free radicals. When exposed to light irradiation (λ > 420 nm), it was found that BiOBr/PtRu hybrid nanostructures not only exhibit improved photocatalytic degradation, but also exhibit enhanced peroxidase- and oxidase-like activity. Due to the photocatalytic effect and the higher charge separation and utilization efficiency caused by heterojunctions, a light-enhanced enzyme-like activity mechanism was proposed. These results will be of value to design high efficiency nanozymes using light for biological and environmental applications.

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来源期刊
CiteScore
4.60
自引率
0.00%
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