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吡啶与α-重氮乙酸盐的光催化烷氧羰基甲基化†

Organic chemistry frontiers : an international journal of organic chemistry Pub Date : 2023-01-01 DOI:10.1039/d2qo01818g
Haisheng Xie , Zhongfeng Luo , Fengjuan Chen , Huanfeng Jiang , Wei Zeng
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引用次数: 0

摘要

研究了2-氨基吡啶与α-重氮乙酸盐的光催化区域选择性烷氧羰基甲基化反应。该方法提供了一种在温和条件下通过直接吡啶基Csp2–H键类碳插入组装2-芳基-2-吡啶乙酸酯的无金属策略。
本文章由计算机程序翻译，如有差异，请以英文原文为准。

Photocatalyzed alkoxycarbonylmethylation of pyridines with α-diazoacetates†

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Photocatalyzed alkoxycarbonylmethylation of pyridines with α-diazoacetates†

A photocatalyzed regioselective alkoxycarbonylmethylation of 2-aminopyridines with α-diazoacetates has been developed. This method provides a metal-free strategy to assemble 2-aryl-2-pyridylacetic esters via a direct pyridyl Csp2–H bond carbenoid insertion under mild conditions.

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Organic chemistry frontiers : an international journal of organic chemistry
Organic chemistry frontiers : an international journal of organic chemistry
CiteScore
7.80
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