邻氟苯甲酸和对氟苯甲酸的燃烧焓和生成焓。

Walter H Johnson, Edward J Prosen
{"title":"邻氟苯甲酸和对氟苯甲酸的燃烧焓和生成焓。","authors":"Walter H Johnson,&nbsp;Edward J Prosen","doi":"10.6028/jres.079A.011","DOIUrl":null,"url":null,"abstract":"<p><p>The enthalpies of combustion and formation of one sample of ortho- and two samples of parafluorobenzoic acids have been determined by combustion in an oxygen-bomb calorimeter. The data obtained by other investigators are discussed briefly. The values obtained and their estimated uncertainties are as follows: [Table: see text] where Δ<i>Hc</i>° corresponds to the reaction: <dispformula> <math> <mrow><msub><mtext>C</mtext> <mn>7</mn></msub> <msub><mtext>H</mtext> <mn>5</mn></msub> <msub><mtext>O</mtext> <mn>2</mn></msub> <mtext>F</mtext> <mo>(</mo> <mtext>c</mtext> <mo>)</mo> <mo>+</mo> <mn>7</mn> <msub><mtext>O</mtext> <mn>2</mn></msub> <mo>(</mo> <mtext>g</mtext> <mo>)</mo> <mo>+</mo> <mn>48</mn> <msub><mtext>H</mtext> <mn>2</mn></msub> <mtext>O</mtext> <mo>(</mo> <mtext>liq</mtext> <mo>)</mo> <mo>→</mo> <mn>7</mn> <msub><mrow><mtext>CO</mtext></mrow> <mn>2</mn></msub> <mo>(</mo> <mtext>g</mtext> <mo>)</mo> <mo>+</mo> <mrow><mo>[</mo> <mrow><mtext>HF</mtext> <mo>+</mo> <mn>50</mn> <msub><mtext>H</mtext> <mn>2</mn></msub> <mtext>O</mtext></mrow> <mo>]</mo></mrow> <mo>(</mo> <mtext>liq</mtext> <mo>)</mo> <mo>.</mo></mrow> </math></dispformula>.</p>","PeriodicalId":17018,"journal":{"name":"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1975-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6589408/pdf/jres-79A-481.pdf","citationCount":"8","resultStr":"{\"title\":\"The Enthalpies of Combustion and Formation of Ortho- and Parafluorobenzoic Acid.\",\"authors\":\"Walter H Johnson,&nbsp;Edward J Prosen\",\"doi\":\"10.6028/jres.079A.011\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The enthalpies of combustion and formation of one sample of ortho- and two samples of parafluorobenzoic acids have been determined by combustion in an oxygen-bomb calorimeter. The data obtained by other investigators are discussed briefly. The values obtained and their estimated uncertainties are as follows: [Table: see text] where Δ<i>Hc</i>° corresponds to the reaction: <dispformula> <math> <mrow><msub><mtext>C</mtext> <mn>7</mn></msub> <msub><mtext>H</mtext> <mn>5</mn></msub> <msub><mtext>O</mtext> <mn>2</mn></msub> <mtext>F</mtext> <mo>(</mo> <mtext>c</mtext> <mo>)</mo> <mo>+</mo> <mn>7</mn> <msub><mtext>O</mtext> <mn>2</mn></msub> <mo>(</mo> <mtext>g</mtext> <mo>)</mo> <mo>+</mo> <mn>48</mn> <msub><mtext>H</mtext> <mn>2</mn></msub> <mtext>O</mtext> <mo>(</mo> <mtext>liq</mtext> <mo>)</mo> <mo>→</mo> <mn>7</mn> <msub><mrow><mtext>CO</mtext></mrow> <mn>2</mn></msub> <mo>(</mo> <mtext>g</mtext> <mo>)</mo> <mo>+</mo> <mrow><mo>[</mo> <mrow><mtext>HF</mtext> <mo>+</mo> <mn>50</mn> <msub><mtext>H</mtext> <mn>2</mn></msub> <mtext>O</mtext></mrow> <mo>]</mo></mrow> <mo>(</mo> <mtext>liq</mtext> <mo>)</mo> <mo>.</mo></mrow> </math></dispformula>.</p>\",\"PeriodicalId\":17018,\"journal\":{\"name\":\"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1975-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6589408/pdf/jres-79A-481.pdf\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.6028/jres.079A.011\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.6028/jres.079A.011","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8

摘要

用氧弹量热计测定了一种邻苯二甲酸和两种对氟苯甲酸的燃烧焓和生成焓。简要讨论了其他研究者获得的数据。得到的值及其估计的不确定度如下:[表:见文]其中ΔHc°对应于反应:c7h5o 2f (C) + 7o2 (g) + 48h2o (liq)→7co2 (g) + [HF + 50h2o] (liq)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Enthalpies of Combustion and Formation of Ortho- and Parafluorobenzoic Acid.

The enthalpies of combustion and formation of one sample of ortho- and two samples of parafluorobenzoic acids have been determined by combustion in an oxygen-bomb calorimeter. The data obtained by other investigators are discussed briefly. The values obtained and their estimated uncertainties are as follows: [Table: see text] where ΔHc° corresponds to the reaction: C 7 H 5 O 2 F ( c ) + 7 O 2 ( g ) + 48 H 2 O ( liq ) 7 CO 2 ( g ) + [ HF + 50 H 2 O ] ( liq ) . .

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信