在同系物反应中使用卤化类锂的实用指南。

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Monatshefte Fur Chemie Pub Date : 2018-01-01 Epub Date: 2018-06-11 DOI:10.1007/s00706-018-2232-9

Serena Monticelli, Marta Rui, Laura Castoldi, Giada Missere, Vittorio Pace

引用次数: 5

摘要

摘要：卤代类锂是完成同源化过程的通用试剂。它们遭受的快速α-消除被认为是其广泛使用的一个重要限制。在此，我们提出了一系列实际考虑因素，以有效利用所选碳亲电试剂的同源性。图形摘要：

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A practical guide for using lithium halocarbenoids in homologation reactions.

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A practical guide for using lithium halocarbenoids in homologation reactions.

Abstract: Lithium halocarbenoids are versatile reagents for accomplishing homologation processes. The fast α-elimination they suffer has been considered an important limitation for their extensive use. Herein, we present a series of practical considerations for an effective employment in the homologation of selected carbon electrophiles.

Graphical abstract:

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来源期刊

Monatshefte Fur Chemie 化学-化学综合

CiteScore

3.70

自引率

5.60%

发文量

116

审稿时长

3.3 months

期刊介绍： "Monatshefte für Chemie/Chemical Monthly" was originally conceived as an Austrian journal of chemistry. It has evolved into an international journal covering all branches of chemistry. Featuring the most recent advances in research in analytical chemistry, biochemistry, inorganic, medicinal, organic, physical, structural, and theoretical chemistry, Chemical Monthly publishes refereed original papers and a section entitled "Short Communications". Reviews, symposia in print, and issues devoted to special fields will also be considered.