由钴催化手性二炔环三聚反应合成的新型萘基吡啶。

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Monatshefte Fur Chemie Pub Date : 2018-01-01 Epub Date: 2017-11-28 DOI:10.1007/s00706-017-2083-9

Volkmar Trommer, Fabian Fischer, Marko Hapke

引用次数: 6

摘要

摘要:介绍了一种用于手性萘基吡啶组装的新型手性二炔底物的简明合成，并研究了钴催化与腈共环三聚化的不同条件。产物是具有构型稳定的双芳基轴的新型萘基吡啶。图形化的简介:

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Novel naphthylpyridines from cobalt-catalyzed cyclotrimerization of a chiral diyne.

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Novel naphthylpyridines from cobalt-catalyzed cyclotrimerization of a chiral diyne.

Abstract: The concise synthesis of a novel chiral diyne substrate for the assembly of chiral naphthylpyridines was described and different conditions for the cobalt-catalyzed co-cyclotrimerization with nitriles investigated. The products are novel naphthylpyridines possessing configurationally stable biaryl axes.

Graphical abstract:

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来源期刊

Monatshefte Fur Chemie 化学-化学综合

CiteScore

3.70

自引率

5.60%

发文量

116

审稿时长

3.3 months

期刊介绍： "Monatshefte für Chemie/Chemical Monthly" was originally conceived as an Austrian journal of chemistry. It has evolved into an international journal covering all branches of chemistry. Featuring the most recent advances in research in analytical chemistry, biochemistry, inorganic, medicinal, organic, physical, structural, and theoretical chemistry, Chemical Monthly publishes refereed original papers and a section entitled "Short Communications". Reviews, symposia in print, and issues devoted to special fields will also be considered.