Sydney M Watkins, Timothy J Hagen, Timothy S Perkins, Chong Zheng
{"title":"(Z)-4-氯-N-{3-[(4-氯苯基)磺酰基]-2,3-二氢苯并[d]噻唑-2-亚基}苯磺酰胺。","authors":"Sydney M Watkins, Timothy J Hagen, Timothy S Perkins, Chong Zheng","doi":"10.1107/S2414314617008653","DOIUrl":null,"url":null,"abstract":"<p><p>The title compound, C<sub>19</sub>H<sub>12</sub>Cl<sub>2</sub>N<sub>2</sub>O<sub>4</sub>S<sub>3</sub>, is related to a ditosylated 2-iminobenzothiazole with the two methyl groups on the two phenyl rings replaced by chlorine. There is a weak intramolecular <i>π</i>-<i>π</i> contact between the two phenyl rings, with a centroid-to-centroid distance of 4.004 (2) Å. The dihedral angle between the rings is 9.96 (13)°. An intramolecular C-H⋯O hydrogen bond stabilizes the molecular conformation.</p>","PeriodicalId":14692,"journal":{"name":"IUCrData","volume":"2 ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5808994/pdf/nihms915086.pdf","citationCount":"0","resultStr":"{\"title\":\"(<i>Z</i>)-4-Chloro-<i>N</i>-{3-[(4-chlorophenyl)sulfonyl]-2,3-dihydrobenzo[<i>d</i>]thiazol-2-ylidene}benzene-sulfonamide.\",\"authors\":\"Sydney M Watkins, Timothy J Hagen, Timothy S Perkins, Chong Zheng\",\"doi\":\"10.1107/S2414314617008653\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The title compound, C<sub>19</sub>H<sub>12</sub>Cl<sub>2</sub>N<sub>2</sub>O<sub>4</sub>S<sub>3</sub>, is related to a ditosylated 2-iminobenzothiazole with the two methyl groups on the two phenyl rings replaced by chlorine. There is a weak intramolecular <i>π</i>-<i>π</i> contact between the two phenyl rings, with a centroid-to-centroid distance of 4.004 (2) Å. The dihedral angle between the rings is 9.96 (13)°. An intramolecular C-H⋯O hydrogen bond stabilizes the molecular conformation.</p>\",\"PeriodicalId\":14692,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"2 \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5808994/pdf/nihms915086.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1107/S2414314617008653\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2017/6/20 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314617008653","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2017/6/20 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
The title compound, C19H12Cl2N2O4S3, is related to a ditosylated 2-iminobenzothiazole with the two methyl groups on the two phenyl rings replaced by chlorine. There is a weak intramolecular π-π contact between the two phenyl rings, with a centroid-to-centroid distance of 4.004 (2) Å. The dihedral angle between the rings is 9.96 (13)°. An intramolecular C-H⋯O hydrogen bond stabilizes the molecular conformation.
![(<i>Z</i>)-4-Chloro-<i>N</i>-{3-[(4-chlorophenyl)sulfonyl]-2,3-dihydrobenzo[<i>d</i>]thiazol-2-ylidene}benzene-sulfonamide.](https://img.booksci.cn/booksciimg/2017-1/202310237812328087447676178.jpg)
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