{"title":"金属硝基配合物的制备、结构特征和物理化学性质。","authors":"Lauren R Holloway, Lijuan Li","doi":"10.1007/430_2013_101","DOIUrl":null,"url":null,"abstract":"<p><p>The preparation and characterization of a representative group of novel non-heme metal nitrosyl complexes that have been synthesized over the last decade are discussed here. Their structures are examined and classified based on metal type, the number of metal centers present, and the type of ligand that is coordinated with the metal. The ligands can be phosphorus, nitrogen, or sulfur based (with a few exceptions) and can vary depending on the presence of chelation, intermolecular forces, or the presence of other ligands. Structural and bonding characteristics are summarized and examples of reactivity regarding nitrosyl ligands are given. Some of the relevant physical chemical properties of these complexes, including IR, EPR, NMR, UV-vis, cyclic voltammetry, and X-ray crystallography are examined.</p>","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":"154 ","pages":"53-98"},"PeriodicalIF":0.0000,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5792085/pdf/nihms875227.pdf","citationCount":"0","resultStr":"{\"title\":\"The Preparation, Structural Characteristics, and Physical Chemical Properties of Metal-Nitrosyl Complexes.\",\"authors\":\"Lauren R Holloway, Lijuan Li\",\"doi\":\"10.1007/430_2013_101\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The preparation and characterization of a representative group of novel non-heme metal nitrosyl complexes that have been synthesized over the last decade are discussed here. Their structures are examined and classified based on metal type, the number of metal centers present, and the type of ligand that is coordinated with the metal. The ligands can be phosphorus, nitrogen, or sulfur based (with a few exceptions) and can vary depending on the presence of chelation, intermolecular forces, or the presence of other ligands. Structural and bonding characteristics are summarized and examples of reactivity regarding nitrosyl ligands are given. Some of the relevant physical chemical properties of these complexes, including IR, EPR, NMR, UV-vis, cyclic voltammetry, and X-ray crystallography are examined.</p>\",\"PeriodicalId\":49469,\"journal\":{\"name\":\"Structure and Bonding\",\"volume\":\"154 \",\"pages\":\"53-98\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5792085/pdf/nihms875227.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Structure and Bonding\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/430_2013_101\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2013/5/29 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q3\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Structure and Bonding","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/430_2013_101","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2013/5/29 0:00:00","PubModel":"Epub","JCR":"Q3","JCRName":"Chemistry","Score":null,"Total":0}
The Preparation, Structural Characteristics, and Physical Chemical Properties of Metal-Nitrosyl Complexes.
The preparation and characterization of a representative group of novel non-heme metal nitrosyl complexes that have been synthesized over the last decade are discussed here. Their structures are examined and classified based on metal type, the number of metal centers present, and the type of ligand that is coordinated with the metal. The ligands can be phosphorus, nitrogen, or sulfur based (with a few exceptions) and can vary depending on the presence of chelation, intermolecular forces, or the presence of other ligands. Structural and bonding characteristics are summarized and examples of reactivity regarding nitrosyl ligands are given. Some of the relevant physical chemical properties of these complexes, including IR, EPR, NMR, UV-vis, cyclic voltammetry, and X-ray crystallography are examined.
期刊介绍：
Structure and Bonding is a publication which uniquely bridges the journal and book format. Organized into topical volumes, the series publishes in depth and critical reviews on all topics concerning structure and bonding. With over 50 years of history, the series has developed from covering theoretical methods for simple molecules to more complex systems.
Topics addressed in the series now include the design and engineering of molecular solids such as molecular machines, surfaces, two dimensional materials, metal clusters and supramolecular species based either on complementary hydrogen bonding networks or metal coordination centers in metal-organic framework materials (MOFs). Also of interest is the study of reaction coordinates of organometallic transformations and catalytic processes, and the electronic properties of metal ions involved in important biochemical enzymatic reactions.
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