新型吡啶基Pd(II)配合物在水中微波辐射下对芳基卤化物进行高效Suzuki偶联。

Q1 Chemistry

Chemistry Central Journal Pub Date : 2017-09-18 DOI:10.1186/s13065-017-0320-2

Ismail I Althagafi, Mohamed R Shaaban, Aisha Y Al-Dawood, Ahmad M Farag

引用次数: 18

摘要

以新型无磷钯配合物为预催化剂，研究了芳基卤化物与芳基硼酸的铃木C-C交联反应。以水为绿色溶剂，在高温和微波条件下制备吡啶基Pd(II)配合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Novel pyridine-based Pd(II)-complex for efficient Suzuki coupling of aryl halides under microwaves irradiation in water.

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Novel pyridine-based Pd(II)-complex for efficient Suzuki coupling of aryl halides under microwaves irradiation in water.

Suzuki C-C cross-coupling of aryl halides with aryl boronic acids using new phosphene-free palladium complexes as precatalysts was investigated. A pyridine-based Pd(II)-complex was used in open air under thermal as well as microwave irradiation conditions using water as an eco-friendly green solvent.

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来源期刊

Chemistry Central Journal 化学-化学综合

CiteScore

4.40

自引率

0.00%

发文量

审稿时长

3.5 months

期刊介绍： BMC Chemistry is an open access, peer reviewed journal that considers all articles in the broad field of chemistry, including research on fundamental concepts, new developments and the application of chemical sciences to broad range of research fields, industry, and other disciplines. It provides an inclusive platform for the dissemination and discussion of chemistry to aid the advancement of all areas of research. Sections: -Analytical Chemistry -Organic Chemistry -Environmental and Energy Chemistry -Agricultural and Food Chemistry -Inorganic Chemistry -Medicinal Chemistry -Physical Chemistry -Materials and Macromolecular Chemistry -Green and Sustainable Chemistry