在含CO2的碱性介质中,锡锌铝合金对铝空气电池电化学性能的影响

IF 8.1 2区 工程技术 Q1 CHEMISTRY, PHYSICAL
Mahmoud Elrouby , Mohamed Abdelsamie , Abdelrahman El-sayed
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引用次数: 2

摘要

采用熔合法制备了铝与锡、锌等金属的合金,研究了合金元素对铝阳极电化学特性的影响。在5 M KOH介质中,对Al-Sn和Al-Zn阳极进行了无CO2和有CO2的缓蚀和电化学试验,并与商业铝进行了比较。Tafel极化表明,在纯KOH中,阳极和阴极分支的电流密度比Al金属低。与Al相比,所研究的合金的开路电压稳态(Ecorr.)转移到更负的量级。在CO2存在下,腐蚀电流急剧下降,电位明显转移到更负的值。这是由于铝、锡和锌的碳酸盐在表面形成了一层保护层。在二氧化碳的情况下,得到了惊人的结果并进行了讨论。电化学阻抗谱(EIS)结果表明,电荷转移电阻(Rct)随合金元素的增加而升高。Tafel图的数据与EIS的数据一致。Al与Sn和Zn元素的合金化对电容、析氢过程抑制和充放电效率有显著影响。这表明,在有CO2存在的充电过程中,Al - zn合金获得的电位值最高,而在有CO2存在的放电过程中,Al获得的电位值最大。此外,合金在无CO2时的放电时间比商用铝的放电时间要长,而在有CO2时则更长。所生产的合金被认为可以为长寿命的可充电电池提供良好的阳极。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Sn and Zn alloying with Al on its electrochemical performance in an alkaline media containing CO2 for Al-air batteries application

Aluminum alloyed with other metals, such as Sn and Zn, was synthesized via fusion to trace the impact of alloying elements on the electrochemical characteristics of Al anodes. The corrosion inhibition and electrochemical tests were performed in a 5 M KOH medium in the absence and presence of CO2 for the Al–Sn, and Al–Zn anodes and compared to the commercial aluminum. Tafel polarization exhibited that the anodic and cathodic branches display lower current densities than Al metal in pure KOH. The steady state of the open circuit voltage (Ecorr.) for the studied alloys was shifted to a more negative magnitude than for Al. The corrosion current is sharply decreased, and potential is significantly shifted to less negative values in the presence of CO2. This is due to forming of a protective layer from the carbonate of Al, Sn, and Zn on the surface. Amazing results were obtained and discussed in the case of CO2. Electrochemical impedance spectroscopy (EIS) results exhibited that charge transfer resistance (Rct) values rise with alloying elements. The data of Tafel plots are consistent with those of EIS. The alloying of Al with Sn and Zn elements significantly affects capacitance, hydrogen evolution process suppression, and charge-discharge efficiency. This reveals that the highest potential value in the presence of CO2 in the charging process is obtained for Al–Zn alloy, while the most negative potential is obtained for Al in the discharging process with CO2. Moreover, the discharge time is higher in the alloys than in commercial Al in the absence and more in the presence of CO2. The produced alloys are thought to provide good anodes for long-life rechargeable batteries.

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来源期刊
International Journal of Hydrogen Energy
International Journal of Hydrogen Energy 工程技术-环境科学
CiteScore
13.50
自引率
25.00%
发文量
3502
审稿时长
60 days
期刊介绍: The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc. The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.
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