A N Siniakov, E B Nikolaenkova, I A Os'kina, V A Savel'ev, V A Samsonov, A Ia Tikhonov, M Iu Palatkina, D E Zaĭtsev
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[Photogenerator of trichloroacetic acid--a perspective detritylation agent for microchip oligonucleotide synthesis].
For the purpose of new detritylation agents search for microarray oligonucleotide synthesis we investigated applicability of [4-(4-methoxyphenyl)-2,6-dinitro-phenyl](phenyl)methyl 2,2,2-trichloroacetate for 4,4'-dimethoxytrityl group detritylation during oligonucleotide syntheses generating trichloroacetic acid at radiation by light with a length of wave of 405 nanometers. [4-(4-Methoxyphenyl)-2,6-dinitro-phenyl](phenyl)methyl 2,2,2-trichloroacetate has been successfully used for solid-phase oligonucleotide synthesis of desired oligonucleotides.
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