（2-{3-[4-（4'-氰基-联苯-4-基-氧基）但氧基]吡啶-2-基-kN}-5-（十二酰氧基）苯基kC（1））（9-氧代-四-cos-7-en-7-olato-k（2）O，O’）铂（II）的晶体结构。

IF 0.9

Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-05 eCollection Date: 2014-12-01 DOI:10.1107/S1600536814021928

Kaijun Luo, Hanlin Liu, Qing Guo, Daibing Luo

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引用次数: 0

摘要

标题化合物[Pt(C40H47N2O3)(C24H45O2)]的中心Pt(II)原子具有轻微畸变的方平面配位环境。Pt与螯合的C、N原子形成的平面与Pt与螯合的O原子形成的平面的二面角为2.1(3)°。在联苯-4-碳腈单元中，两个环的平面夹角为35.1(5)°。一条侧烷烃链在两组位点上无序分布，位点占用系数为0.595(7):0.405(7)。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Crystal structure of (2-{3-[4-(4'-cyano-biphenyl-4-yl-oxy)but-oxy]pyridin-2-yl-κN}-5-(dodec-yloxy)phenyl-κC (1))(9-oxo-tetra-cos-7-en-7-olato-κ(2) O,O')platinum(II).

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Crystal structure of (2-{3-[4-(4'-cyano-biphenyl-4-yl-oxy)but-oxy]pyridin-2-yl-κN}-5-(dodec-yloxy)phenyl-κC (1))(9-oxo-tetra-cos-7-en-7-olato-κ(2) O,O')platinum(II).

The central Pt(II) atom in the title compound, [Pt(C40H47N2O3)(C24H45O2)], has a slightly distorted square-planar coordination environment. The dihedral angle between the plane formed by Pt and the chelating C and N atoms and that formed by Pt and the chelating O atoms is 2.1 (3)°. The angle between the planes of the two rings in the biphenyl-4-carbo-nitrile unit is 35.1 (5)°. One lateral alkane chain is disordered over two sets of sites with site occupancy factors in a 0.595 (7):0.405 (7) ratio.

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来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

期刊介绍： Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.