1,1'-双-[1,2-二碳-近十二硼烷[11]的确定晶体结构。

IF 0.9
Wing Y Man, Georgina M Rosair, Alan J Welch
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引用次数: 8

摘要

在标题化合物C4H22B20中,两个{1,2- close - c2b10h11}笼穿过反转中心连接,C-C距离为1.5339 (11)Å。通过对结构的仔细分析,确定了非连接笼C原子在笼顶点2和3上具有同样的无序性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Definitive crystal structure of 1,1'-bis-[1,2-dicarba-closo-dodeca-borane(11)].

Definitive crystal structure of 1,1'-bis-[1,2-dicarba-closo-dodeca-borane(11)].

Definitive crystal structure of 1,1'-bis-[1,2-dicarba-closo-dodeca-borane(11)].

Definitive crystal structure of 1,1'-bis-[1,2-dicarba-closo-dodeca-borane(11)].

In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C-C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3.

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来源期刊
自引率
33.30%
发文量
0
审稿时长
1.3 months
期刊介绍: Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.
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