含1-苯基- 1h -1,2,3,4-四唑-5-硫醇配体的二维Cu(I)框架。

IF 0.8 4区化学

Acta crystallographica. Section C, Crystal structure communications Pub Date : 2013-12-15 Epub Date: 2013-11-08 DOI:10.1107/S0108270113029065

Fang-Xia Zhou, Cheng-Yang Yue, Hui-Ping Zhang, Xiao-Wu Lei

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引用次数: 4

摘要

在乙腈-丙酮溶液中，用cur与1-苯基- 1h -1,2,3,4-四唑-5-硫醇(Hptt)反应，在溶剂热条件下制备了新型二维配位聚合物聚[(μ4-1-苯基- 1h -1,2,3,4-四唑-5-硫醇)铜(I)]， [Cu(C7H5N4S)]n。在晶体结构中，每个Cu(I)离子由来自四个ptt(-)配体的两个N原子和两个S原子配位，每个ptt(-)配体连接四个Cu(I)离子形成平行于(100)平面的二维层。这些层通过范德华相互作用沿[100]方向堆叠。

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A two-dimensional Cu(I) framework incorporating the 1-phenyl-1H-1,2,3,4-tetrazole-5-thiol ligand.

The new two-dimensional coordination polymer, poly[(μ4-1-phenyl-1H-1,2,3,4-tetrazole-5-thiolato)copper(I)], [Cu(C7H5N4S)]n, has been prepared under solvothermal conditions by reacting CuBr with 1-phenyl-1H-1,2,3,4-tetrazole-5-thiol (Hptt) in an acetonitrile and acetone solution. In the crystal structure, each Cu(I) ion is coordinated by two N atoms and two S atoms from four ptt(-) ligands, and each ptt(-) ligand links four Cu(I) ions to form two-dimensional layers which lie parallel to the (100) plane. These layers stack along the [100] direction via van der Waals interactions.

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来源期刊

Acta crystallographica. Section C, Crystal structure communications 化学-晶体学

自引率

12.50%

发文量

审稿时长

1 months

期刊介绍： Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.