有机-无机杂化材料1-环己基哌嗪-1,4-四氯肼二钠。

IF 0.8 4区化学

Acta crystallographica. Section C, Crystal structure communications Pub Date : 2013-11-01 Epub Date: 2013-10-05 DOI:10.1107/S0108270113026267

Sarra Soudani, Emmanuel Aubert, Christian Jelsch, Cherif Ben Nasr

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引用次数: 6

摘要

在标题有机-无机杂化材料(C10H22N2)[ZnCl4]的晶体结构中，四氯碘酸盐阴离子和1-环己基哌嗪-1,4-二氮通过N-H…Cl和碳氢键…Cl氢键形成平行于(001)平面的层。相邻链上的环己基互指，从而形成三维结构。哌嗪环和环己基环呈规则的空间椅子构象。并用FT-IR和拉曼光谱对标题盐进行了表征。

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The organic-inorganic hybrid material 1-cyclohexylpiperazine-1,4-diium tetrachloridozincate.

In the crystal structure of the title organic-inorganic hybrid material, (C10H22N2)[ZnCl4], the tetrachloridozincate anions and 1-cyclohexylpiperazine-1,4-diium dications are interconnected via N-H...Cl and C-H...Cl hydrogen bonds to form layers parallel to the (001) plane. The cyclohexyl groups from adjacent chains interdigitate, thus building the three-dimensional structure. The piperazinium and cyclohexyl rings exhibit regular spatial chair conformations. The title salt was also characterized by FT-IR and Raman spectroscopic analyses.

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来源期刊

Acta crystallographica. Section C, Crystal structure communications 化学-晶体学

自引率

12.50%

发文量

审稿时长

1 months

期刊介绍： Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.