从粉末XRD数据中提炼出双钼酸盐Na9Sc(MoO4)6。

IF 0.8 4区化学

Acta crystallographica. Section C, Crystal structure communications Pub Date : 2013-11-01 Epub Date: 2013-10-31 DOI:10.1107/S010827011302862X

Aleksandra A Savina, Vladimir A Morozov, Olga M Basovich, Elena G Khaikina, Bogdan I Lazoryak

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引用次数: 9

摘要

采用固相法合成了Na9Sc(MoO4)6{六烷基非钠钪[四氧化钼酸盐(II)]}。基本结构单元是由一个ScO6八面体和三个共用总边的NaO6八面体组成的多面体簇。这些簇通过与桥接的MoO4四面体共享顶点来连接，形成一个三维框架，其中空腔由另外两个晶体学独立的Na原子占据。

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The double molybdate Na9Sc(MoO4)6 refined from powder XRD data.

Na9Sc(MoO4)6 {nonasodium scandium hexakis[tetraoxidomolybdate(II)]} was synthesised by a solid-state method. The basic structure units are polyhedral clusters composed of an ScO6 octahedron and three NaO6 octahedra sharing total edges. The clusters are connected by sharing vertices with bridging MoO4 tetrahedra, forming a three-dimensional framework where the cavities are occupied by the other two crystallographically independent Na atoms.

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来源期刊

Acta crystallographica. Section C, Crystal structure communications 化学-晶体学

自引率

12.50%

发文量

审稿时长

1 months

期刊介绍： Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.