{"title":"氨基酸合成的新技巧:应用于复杂的天然产品。","authors":"Robert M Williams, Cameron M Burnett","doi":"","DOIUrl":null,"url":null,"abstract":"<p><p>We report the application of diphenyloxazinone glycinate chiral templates to asymmetric syntheses of cylindrospermospin, 7-epi-cylindrospermopsin, 7-deoxycylindrospermopsin, and spirotryprostatins A and B. Synthetic studies toward quinine, nakadomarin A, and palau'amine using these templates are also described.</p>","PeriodicalId":72050,"journal":{"name":"ACS symposium series. American Chemical Society","volume":"1009 ","pages":"420-442"},"PeriodicalIF":0.0000,"publicationDate":"2009-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2886987/pdf/nihms178104.pdf","citationCount":"0","resultStr":"{\"title\":\"New Tricks in Amino Acid Synthesis: Applications to Complex Natural Products.\",\"authors\":\"Robert M Williams, Cameron M Burnett\",\"doi\":\"\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>We report the application of diphenyloxazinone glycinate chiral templates to asymmetric syntheses of cylindrospermospin, 7-epi-cylindrospermopsin, 7-deoxycylindrospermopsin, and spirotryprostatins A and B. Synthetic studies toward quinine, nakadomarin A, and palau'amine using these templates are also described.</p>\",\"PeriodicalId\":72050,\"journal\":{\"name\":\"ACS symposium series. American Chemical Society\",\"volume\":\"1009 \",\"pages\":\"420-442\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2009-06-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2886987/pdf/nihms178104.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS symposium series. American Chemical Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS symposium series. American Chemical Society","FirstCategoryId":"1085","ListUrlMain":"","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
我们报告了二苯基噁嗪酮甘氨酸手性模板在不对称合成圆柱精蛋白、7-表环状吲哚精蛋白、7-脱氧环状吲哚精蛋白、螺螺芪 A 和 B 中的应用。
New Tricks in Amino Acid Synthesis: Applications to Complex Natural Products.
We report the application of diphenyloxazinone glycinate chiral templates to asymmetric syntheses of cylindrospermospin, 7-epi-cylindrospermopsin, 7-deoxycylindrospermopsin, and spirotryprostatins A and B. Synthetic studies toward quinine, nakadomarin A, and palau'amine using these templates are also described.