微型光电倍增管自动流动注射化学发光仪的设计,用于监测海水中铁的皮摩尔浓度。

Andrew R Bowie, Eric P Achterberg, Simon Ussher, Paul J Worsfold
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引用次数: 18

摘要

介绍了一种基于流动注入(FI)的仪器,在LabVIEW控制下监测海水中的铁。该仪器包含一个微型、低功率光电倍增管(PMT),以及一些微电子和电磁驱动阀和蠕动泵。该软件可以完全控制所有流动注入组件并处理来自PMT的数据。优化后的系统每小时可进行20次注射,包括预浓缩和清洗步骤。在海上检测限(空白的3 sd)为21 pM,线性范围为21-2000 pM,样品加载时间为60秒。在线性范围内,重复FI峰之间的典型精度为5.9 +/- 3.2% (n =4)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Design of an automated flow injection-chemiluminescence instrument incorporating a miniature photomultiplier tube for monitoring picomolar concentrations of iron in seawater.

A flow-injection (FI)-based instrument under LabVIEW control for monitoring iron in marine waters is described. The instrument incorporates a miniature, low-power photomultiplier tube (PMT), and a number of microelectric and solenoid actuated valves and peristaltic pumps. The software allows full control of all flow injection components and processing of the data from the PMT. The optimised system is capable of 20 injections per hour, including preconcentration and wash steps. The detection limit (3 sd of the blank) is 21 pM at sea and the linear range is 21-2000 pM with a 60-second sample load time. Typical precision between replicate FI peaks is 5.9 +/- 3.2 % (n =4) over the linear range.

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