用于高能水电池的上升锌阳极

IF 22.2 Q1 CHEMISTRY, MULTIDISCIPLINARY
Lintong Hu , Ping Xiao , Lanlan Xue , Huiqiao Li , Tianyou Zhai
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引用次数: 59

摘要

锌金属水电池因其安全性高、容量大、成本效益好、环境友好等优点而受到广泛关注。但锌阳极长期存在枝晶形成、循环寿命差、库仑效率低等问题,严重阻碍了锌阳极的实际应用。本文综述了锌金属水电池用锌金属阳极的最新研究进展。首先综述了锌金属阳极的优点、在不同介质中的反应机理以及面临的问题。重点介绍了锌阳极在水介质中的研究进展,包括电解质优化、基质构建、界面修饰、阳极结构设计和工作模式调整等。最后,对锌阳极存在的挑战进行了充分的讨论,并提出了通过多策略集成、锌电镀/剥离行为原位研究、探索先进阴极材料和开发智能器件等方法寻求稳定锌金属阳极的未来展望。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The rising zinc anodes for high-energy aqueous batteries

The rising zinc anodes for high-energy aqueous batteries

Aqueous zinc-metal batteries have gained widespread attention because of their high safety, large capacity, cost effectiveness, and environmental friendliness. However, zinc anodes have long encountered with dendrite formation, inferior cycle life and low coulombic efficiency, which severely hinder the practical application. Here, the latest advances of zinc metal anodes for aqueous zinc-metal batteries are reviewed. The merits of zinc metal anodes, the reaction mechanisms in different media, and the issues faced are firstly summarized. Then the prominent progresses of zinc anodes in aqueous media are highlighted, including electrolyte optimization, host construction, interface modification, anode structure design, and working model regulation. Finally, the remaining challenges of zinc anodes are fully discussed, and the future perspectives of pursing stable zinc metal anodes by integrating multi-strategies, conducting in situ study of zinc plating/stripping behavior, exploring advanced cathode materials, and developing smart devices are also provided.

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来源期刊
EnergyChem
EnergyChem Multiple-
CiteScore
40.80
自引率
2.80%
发文量
23
审稿时长
40 days
期刊介绍: EnergyChem, a reputable journal, focuses on publishing high-quality research and review articles within the realm of chemistry, chemical engineering, and materials science with a specific emphasis on energy applications. The priority areas covered by the journal include:Solar energy,Energy harvesting devices,Fuel cells,Hydrogen energy,Bioenergy and biofuels,Batteries,Supercapacitors,Electrocatalysis and photocatalysis,Energy storage and energy conversion,Carbon capture and storage
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