G. Thejas Urs , Radhika V. Hurkadli , R.V. Basavaraj , M. Niranjana , A. Manjunath , R. Somashekar
{"title":"FeCl3掺杂PVA聚合物的光学和导电性能研究","authors":"G. Thejas Urs , Radhika V. Hurkadli , R.V. Basavaraj , M. Niranjana , A. Manjunath , R. Somashekar","doi":"10.1016/j.pcrysgrow.2014.09.003","DOIUrl":null,"url":null,"abstract":"<div><p>In the present work, PVA and various concentrations of FeCl<sub>3</sub> doped PVA polymer were prepared and optical studies like IR and UV/Visible analysis were carried out on them in solution form also the cast films were examined for their conductance. The variation of optical band gap of PVA polymer with the addition of Fe<sup>3+</sup><span> transition metal ion<span> has been determined by the Tauc plot method. It is found that the optical band gap and the transmittance<span> of the polymer solutions being decreased with the increase in the concentration of Fe</span></span></span><sup>3+</sup><span> ion, and thus obeys Beer's Law. This is supported by conductivity obtained for these polymers and FT-IR spectra which shows the stretching of the various bonds of the polymer due to the addition of transition metal (Fe</span><sup>3+</sup>) ions.</p></div>","PeriodicalId":409,"journal":{"name":"Progress in Crystal Growth and Characterization of Materials","volume":null,"pages":null},"PeriodicalIF":4.5000,"publicationDate":"2014-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.pcrysgrow.2014.09.003","citationCount":"17","resultStr":"{\"title\":\"Study of optical and conducting properties of FeCl3 doped PVA polymers\",\"authors\":\"G. Thejas Urs , Radhika V. Hurkadli , R.V. Basavaraj , M. Niranjana , A. Manjunath , R. Somashekar\",\"doi\":\"10.1016/j.pcrysgrow.2014.09.003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In the present work, PVA and various concentrations of FeCl<sub>3</sub> doped PVA polymer were prepared and optical studies like IR and UV/Visible analysis were carried out on them in solution form also the cast films were examined for their conductance. The variation of optical band gap of PVA polymer with the addition of Fe<sup>3+</sup><span> transition metal ion<span> has been determined by the Tauc plot method. It is found that the optical band gap and the transmittance<span> of the polymer solutions being decreased with the increase in the concentration of Fe</span></span></span><sup>3+</sup><span> ion, and thus obeys Beer's Law. This is supported by conductivity obtained for these polymers and FT-IR spectra which shows the stretching of the various bonds of the polymer due to the addition of transition metal (Fe</span><sup>3+</sup>) ions.</p></div>\",\"PeriodicalId\":409,\"journal\":{\"name\":\"Progress in Crystal Growth and Characterization of Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2014-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/j.pcrysgrow.2014.09.003\",\"citationCount\":\"17\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Progress in Crystal Growth and Characterization of Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0960897414000254\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Crystal Growth and Characterization of Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0960897414000254","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
Study of optical and conducting properties of FeCl3 doped PVA polymers
In the present work, PVA and various concentrations of FeCl3 doped PVA polymer were prepared and optical studies like IR and UV/Visible analysis were carried out on them in solution form also the cast films were examined for their conductance. The variation of optical band gap of PVA polymer with the addition of Fe3+ transition metal ion has been determined by the Tauc plot method. It is found that the optical band gap and the transmittance of the polymer solutions being decreased with the increase in the concentration of Fe3+ ion, and thus obeys Beer's Law. This is supported by conductivity obtained for these polymers and FT-IR spectra which shows the stretching of the various bonds of the polymer due to the addition of transition metal (Fe3+) ions.
期刊介绍:
Materials especially crystalline materials provide the foundation of our modern technologically driven world. The domination of materials is achieved through detailed scientific research.
Advances in the techniques of growing and assessing ever more perfect crystals of a wide range of materials lie at the roots of much of today''s advanced technology. The evolution and development of crystalline materials involves research by dedicated scientists in academia as well as industry involving a broad field of disciplines including biology, chemistry, physics, material sciences and engineering. Crucially important applications in information technology, photonics, energy storage and harvesting, environmental protection, medicine and food production require a deep understanding of and control of crystal growth. This can involve suitable growth methods and material characterization from the bulk down to the nano-scale.