含氧分子在过渡金属碳化物上的反应:表面科学对催化和电催化潜在应用的洞察

IF 8.2 1区 化学 Q1 CHEMISTRY, PHYSICAL
Alan L. Stottlemyer , Thomas G. Kelly , Qinghe Meng , Jingguang G. Chen
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引用次数: 80

摘要

从历史上看,人们对过渡金属碳化物(TMC)催化性能的兴趣是受到它们在烃分子转化反应中的“类铂”性质的启发。然而,最近的研究表明,含氧分子的反应途径在tmc和pt族金属之间有显著差异。尽管如此,tmc在一些重要的催化和电催化应用(包括水电解、醇电氧化、生物质转化和水煤气转移反应)中,无论是作为催化剂还是作为支持金属催化剂的催化活性底物,都表现出了对含氧分子的有趣催化性能。本文综述了TMC表面与含氧分子(包括无机分子(O2、H2O、CO和CO2)和有机分子(醇、醛、酸和酯)相互作用的理论和实验研究。我们将讨论反应途径的一般趋势,以及表面科学研究的未来研究机会,以促进tmc作为催化剂和电催化剂的利用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Reactions of oxygen-containing molecules on transition metal carbides: Surface science insight into potential applications in catalysis and electrocatalysis

Historically the interest in the catalytic properties of transition metal carbides (TMC) has been inspired by their “Pt-like” properties in the transformation reactions of hydrocarbon molecules. Recent studies, however, have revealed that the reaction pathways of oxygen-containing molecules are significantly different between TMCs and Pt-group metals. Nonetheless, TMCs demonstrate intriguing catalytic properties toward oxygen-containing molecules, either as the catalyst or as the catalytically active substrate to support metal catalysts, in several important catalytic and electrocatalytic applications, including water electrolysis, alcohol electrooxidation, biomass conversion, and water gas shift reactions. In the current review we provide a summary of theoretical and experimental studies of the interaction of TMC surfaces with oxygen-containing molecules, including both inorganic (O2, H2O, CO and CO2) and organic (alcohols, aldehydes, acids and esters) molecules. We will discuss the general trends in the reaction pathways, as well as future research opportunities in surface science studies that would facilitate the utilization of TMCs as catalysts and electrocatalysts.

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来源期刊
Surface Science Reports
Surface Science Reports 化学-物理:凝聚态物理
CiteScore
15.90
自引率
2.00%
发文量
9
审稿时长
178 days
期刊介绍: Surface Science Reports is a journal that specializes in invited review papers on experimental and theoretical studies in the physics, chemistry, and pioneering applications of surfaces, interfaces, and nanostructures. The topics covered in the journal aim to contribute to a better understanding of the fundamental phenomena that occur on surfaces and interfaces, as well as the application of this knowledge to the development of materials, processes, and devices. In this journal, the term "surfaces" encompasses all interfaces between solids, liquids, polymers, biomaterials, nanostructures, soft matter, gases, and vacuum. Additionally, the journal includes reviews of experimental techniques and methods used to characterize surfaces and surface processes, such as those based on the interactions of photons, electrons, and ions with surfaces.
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