以分子碘为温和高效催化剂的乙腈中叔丁基酯的化学选择性水解

IF 1.5 4区化学 Q3 CHEMISTRY, ORGANIC

Tetrahedron Letters Pub Date : 2006-07-12 DOI:10.1016/j.tetlet.2006.05.011

J.S. Yadav, E. Balanarsaiah, S. Raghavendra, M. Satyanarayana

引用次数: 20

摘要

介绍了一种简单、温和、高效的以分子碘为催化剂水解叔丁基酯的方法。在反应条件下，N-Boc、OBn、OAc和双键等酸不稳定保护基团是相容的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Chemoselective hydrolysis of tert-butyl esters in acetonitrile using molecular iodine as a mild and efficient catalyst

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Chemoselective hydrolysis of tert-butyl esters in acetonitrile using molecular iodine as a mild and efficient catalyst

A simple, mild and efficient method for the hydrolysis of tert-butyl esters using molecular iodine as a catalyst is described. Acid labile protecting groups, such as N-Boc, OBn, OAc and double bonds, are compatible under the reaction conditions.

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来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.